ISSN 0430-6252. Physicochemical Mechanics of Materials. 2023.
Volume 59, Issue 4

Compacting of material by combining spark plasma sintering and self-expanding high temperature synthesis in Ti–Al–C system

Keywords

spark plasma sintering, seals, metal-matrix composite, self-expanding high-temperature synthesis.

Cite as

Kuskova N. I., Syzonenko O. M., Prystash M. S., and Torpakov A. S. Compacting of material by combining spark plasma sintering and self-expanding high temperature synthesis in Ti–Al–C system. Physicochemical Mechanics of Materials. 2023. 59(4), 75-81.

https://doi.org/10.15407/pcmm2023.04.075

Abstract

Initiation of self-expanding high-temperature synthesis (SHS) in Al–Ti–C system in the process of spark plasma sintering (SPS) of specimens allows obtaining a material with high density, which contains MAX-phases. A simple rheological theory has been develo­ped, which can describe SHS  and SPS processes under certain conditions. Within the framework of this model, the processes of pressing and extrusion at uniaxial pressure are considered. It is shown that the dependence of relative density of powder miture on time is scaled by the factor of the ratio of pressure to toughness of the invariant base of the material. Analytical time dependences of the plunger speed and sample height, as well as the time required to achieve the speci­fied value of the relative density of the Al–Ti–C material, which allows us to predict and analyze the compression of powder mixtures in the IPS process are obtained.

References

  1. V. E. Ovcharenko, and O. V. Lapshyn, “Evolution of the grain structure during the extrusion of an intermetallic compound Ni3Al in the process of high-temperature synthesis under pressure. I. Mathematical model,” Fizika i Khimiya Obrabotki Materialov [in Ukrainian], 3, 76-83 (2007).
  2. V. V. Skorokhod, Rheological Foundations of the Theory of Sintering [in Russian], Naukova Dumka, Kyiv (1972).
  3. V. M. Gorokhov, and M. S. Kovalchenko, “Modern ideas about the mechanism of behavior of Powder Materials during Hot Pressing,” in: Rheological Models and Deformation Processes of Porous and Powder Composite Materials [in Russian], Naukova Dumka, Kyiv (1985), pp. 126-135.
  4. L. M. Buchatskii, A. M. Stolin, and S. I. Khudyaev, “Kinetics of the change of density distribution in hot one-sided pressing of a viscous porous body,” Poroshk. Metall., 25, No. 9, 733-737 (1986). https://doi.org/10.1007/BF00797303
  5. J. Happel, Hydrodynamics at Small Reynolds Numbers [in Russian], Mir, Moscow (1976).
  6. C.-C. Zhu, J. Zhu, H. Wu, and H. Lin, “Synthesis of Ti3AlC2 by SHS and thermodynamic calculation based on first principles,” Rare Metals, 34, Is. 2, 107-110 (2015). https://doi.org/10.1007/s12598-013-0174-2
  7. Yu. E. Sheludiak, Thermophysical Properties of Components of Combustible System [in Russian], Publ. House of Technical and Economic Information, Moscow (1992).
  8. L. S. Stelmakh, and A. M. Stolin, “Thermal regimes of compaction during combustion of powder material,” Doklady RAN [in Russian], 373, No. 2, 206-209 (2000).
  9. L. S. Stelmakh, N. N. Zhyliayeva, and A. M. Stolin, “Rheodynamics and heat exchange of hot compaction of powder materials,” Inzhynerno Tekhnicheskii Zhurnal [in Russian], 63, Is. 5, 612-622 (1992). https://doi.org/10.1007/BF00853510
  10. L. P. Shvedov, “Rheodynamic Model of SBS Processes in the Ti-Al-C System,” in: Abstracts of All-Union Sci. Conf. “Modern Technologies of Material Processing” (Mykolaiv, Nov. 1-2, 2018), Publ. House “Mykolaiv Oblasna Drukarnia”, Mykolaiv (2018), p. 32.
  11. A. D. Rud, A. M. Lakhnik, I. M. Kirian, O. N. Sizonenko, A. D. Zaychenko, N. S. Pristash, and N. D. Rud, “Mechanochemical synthesis and structure of metal-carbon composites based on the MAX phases,” Materials Today: Proc., 5, Is. 12, 26084-26088 (2018). https://doi.org/10.1016/j.matpr.2018.08.034
  12. D. I. Chelpanov, A. N. Yushchishina, and N. I. Kuskova, “Self-propagating high-temperature synthesis in a Ti−Al−C powder system using different carbon precursors,” Surf. Eng. and Appl. Electrochem., 55, Is. 3, 349-356 (2019). https://doi.org/10.3103/S1068375519030049
  13. A. N. Yushchishina, D. I. Chelpanov, and N. I. Kuskova, “Thermodynamic description of chemical reactions in a titanium-aluminum-hexamethylenetetramine system under conditions of self-propagating, high temperature synthesis,” Surf. Eng. and Appl. Electrochem., 56, Is. 4, 469-473 (2020). https://doi.org/10.3103/S1068375520040171
  14. O. M. Syzonenko, A. I. Ivliyev, and Ye. H. Grigoriyev, The Device for Obtaining Consolidated Powder Materials [in Ukrainian], Patent of Ukraine for Invention No. 107729, Publ. on 02.10.2015, Bull. No. 3.
  15. M. X. Zhang, and Y. A. Chang, “Phase diagrams of Ti-Al-C, Ti-Y-O, Nb-Y-O, and Nb-Al-O at 1100°C,” J. of Phase Equilibria, 15, Is. 5, 470-472 (1994). https://doi.org/10.1007/BF02649396
  16. N. A. Svidonovuch, G. P. Okatova, and D. V. Kuis, Materials Science and Construction Materials Technology: Laboratory Practice Using a Metallographic Complex [in Russian], Publ. House of Bielorus. Gos. Tekhn. Univ., Minsk (2007).
  17. A. K. Valeeva, and I. S. Valeev, “On the microhardness and microstructure of copper Cu99,99% at radial-shear rolling,” Lett. Mater., 3, Is. 1, 38-40 (2013). https://doi.org/10.22226/2410-3535-2013-1-38-40