ISSN 3041-1815. Physicochemical Mechanics of Materials. 2026.
Volume 62, Issue 1

Design optimization of Pb–Sn–Сa cast grids for VLRA-batteries

Keywords

lead-acid VLRA-batteries, gravity cast grids, calculation of stress-strain state, optimization of grid design.

Cite as

Dzenzerskiy V. О., Tarasov S. V., Sukhova О. V., and Ivanov V. А. Design optimization of Pb–Sn–Сa cast grids for VLRA-batteries. Physicochemical Mechanics of Materials. 2026. 62(1), 147-152.

https://doi.org/10.15407/pcmm2026.01.147

Abstract

Optimal design of cast grids for lead-acid batteries was chosen. Grids were gravity cast of Pb–Sn–Ca alloys (0.6–0.9 wt% Sn; 0.06–0.09 wt% Сa; Pb – balance) in casting machines of production line for VRLA-batteries of BM company (Austria). The necessary changes introduced to the grid design was estimated based on stress-strain state analysis using ANSYS specialized program. From the considered nine variants of grid design, the use of additional third jumper at the junction of single grids into double grid and diagonal wire with a large angle of inclination in the grid plane was recommen­ded. The proposed changes to the grid design proved to be effective to prevent grids defor­mation in VLRA-batteries production conditions.

References

  1. D.A.J. Rand, Т. Moseley, J. Garche, and C D. Parker, Valve-Regulated Lead-Acid Batteries, Elsevier, Amsterdam (2004). – 576 p.
  2. S. Guruswamy, Engineering Properties and Applications of Lead Alloys, Boca Raton CRC Press (2000). https://doi.org/10.1201/9781482276909
  3. D. Pavlov, Lead-Acid Batteries: Science and Technology, Elsevier, London (2017).
  4. P. Rys, M. Siekierski, M. Knos, and P. Moszczynski, “Trends and prospects in lead-acid battery development,” J. Power Technol., 104, Is. 1, 67-85 (2024).
  5. D.A. J. Rand, D.P. Boden, C.S. Lakshmi, R.R. Nelson, and R.D. Prengaman, “Manufacturing and operational issues with lead-acid batteries,” J. Power Sources, 107, Is. 2, 280-300 (2002). https://doi.org/10.1016/S0378-7753(01)01083-7
  6. K. Sawai, Y. Tsuboi, Y. Okada, M. Shiomi, and S. Osumi, “New approach to prevent premature capacity loss of lead-acid battery in cycle use,” J. Power Sources, 179, Is. 2, 799-807 (2008). https://doi.org/10.1016/j.jpowsour.2007.12.106
  7. R.D. Prengaman, “The metallurgy and performance of cast and rolled lead alloys for battery grids,” J. Power Sources, 67, Is. 1-2, 267-278 (1997). https://doi.org/10.1016/S0378-7753(97)02512-3
  8. V.О. Dzenzerskiy, S.V. Таrasov, O.V. Sukhova, and V.А. Ivanov, “Effects of composition and cooling rate on mechanical properties of Pb-Sb-Sn-As grid alloys,” Rom. J. Phys., 69, Iss. 1-2 (2024). Art. no. 605.
  9. V.О. Dzenzerskiy, S.V. Таrasov, O.V. Sukhova, and V.А. Ivanov, “Evolution of mechanical properties of Pb-Sb-Sn-As-Se grid alloys for lead-acid batteries during natural aging,” East Eur. J. Phys., Is. 4, 182-188 (2023). https://doi.org/10.26565/2312-4334-2023-4-21
  10. J. Furukawa, Y. Nehyo, and S. Shiga, “Development of new positive-grid alloy and its application to long-life batteries for automotive industry,” J. Power Sources, 133, Is. 1, 25-31 (2003). https://doi.org/10.1016/j.jpowsour.2003.12.022
  11. О.V. Sukhova, “Effect of Ti, Al, Si on the structure and mechanical properties of boron-rich Fe-B-C alloys,” East Eur. J. Phys., Is. 2, 115-121 (2021).
  12. V.O. Dzenzerskiy, S.V. Таrasov, D.O. Redchyts, V.А. Ivanov, and O.V. Sukhova, “Mechanical properties of Pb-Sn-Ba grid alloys for lead-acid batteries produced by melt spinning technology,” J. Nano-Electron. Phys., 16, Is. 1 ( 2024). Art. no. 01003. https://doi.org/10.21272/jnep.16(1).01003
  13. C.S. Lakshmi, J.E. Manders, and D.M. Rice, “Structure and properties of lead-calcium-tin alloys for battery grids,” J. Power Sources, 73, Is. 1, 23-29 (1998). https://doi.org/10.1016/S0378-7753(98)00018-4
  14. R.D. Prengaman, “Wrought lead calcium tin alloys for tubular lead-acid-battery grids,” J. Power Sources, 53, Is. 2, 207-214 (1995). https://doi.org/10.1016/0378-7753(94)01975-2
  15. F.A. Pérez-González, C.G. Camurri, C.A. Carrasco, and R. Colás, “Precipitation in a lead calcium tin anode,” Materials Characterization, 64, 62-68 (2012). https://doi.org/10.1016/j.matchar.2011.11.013
  16. A. Maitre, G. Bourguignon, J. M. Fiorani, J. Ghanbaja, and J. Steinmetz, “Precipitation hardening in Pb-0.08 wt%Ca-x% Sn alloys – the role of the pre-ageing,” Mater. Sci. Eng. A, 358, Is. 1-2, 233-242 (2003). https://doi.org/10.1016/S0921-5093(03)00283-1
  17. Y.A. Yassine, M. Lakhal, N. Labchir, E. Zantalla, E. Saad, and M. Sannad, “Kinetic study of the aging and overaging of alloy Pb0.058%Ca0.12%Sr1.09%Sn for battery grids,” Coatings, 13, Is. 9, 1534 (2023). https://doi.org/10.3390/coatings13091534
  18. B. Trembach, Y. Silchenko, O. Balenko, D. Hlachev, K. Kulahin, H. Heiko, O. Bellorin-Herrera, S. Khabosha, O. Zakovorotnyi, and I. Trembach, “Study of the hardfacing process using self-shielding flux-cored wire with an exothermic addition with a combined oxidizer of the Al-(CuO/Fe2O3) system,” Int. J. Adv. Manuf. Technol., 134, Iss. 1-2, 309-335 (2024). https://doi.org/10.1007/s00170-024-14115-4
  19. M. Krbata, M. Kohutiar, J. Escherova, P. Klučiar, Z. Studeny, B. Trembach, N. Beronská, A. Breznická, and Ľ. Timárová, “Continuous cooling transformation of tool steels X153CrMoV12 and 100MnCrW4: analysis of microstructure and hardness changes,” Appl. Mech., 6, Is. 1, 16 (2025). https://doi.org/10.3390/applmech6010016
  20. О.V. Sukhova, “The effect of iron on precipitation hardening in the Cu-Ni-Mn alloys,” Phys. Chem. Solid State, 22, Is. 3, 487-493 (2021). https://doi.org/10.15330/pcss.22.3.487-493
  21. H. Tsubakino, M. Tagami, S. Ioku, and A. Yamamoto, “Precipitation in lead-calcium alloys containing tin,” Metall. Mater. Trans. A, 27, Is. 6, 1675-1682 (1996). https://doi.org/10.1007/BF02649824
  22. R.D. Prengaman “Challenges from corrosion-resistant grid alloys in lead acid battery manufacturing,” J. Power Sources, 95, Is. 1, 224-233 (2001). https://doi.org/10.1016/S0378-7753(00)00620-0
  23. E. Rocca, G. Bourguignon, and J. Steinmetz, “Corrosion management of PbCaSn alloys in lead-acid batteries: effect of composition, metallographic state and voltage conditions,” J. Power Sources, 161, Is. 1, 666-675 (2006). https://doi.org/10.1016/j.jpowsour.2006.04.140
  24. H. Li, W. X. Guo, H. Y. Chen, D. E. Finlow, H. W. Zhou, C. L. Dou, G. M. Xiao, S. G. Peng, W. W. Wei, and H. Wang, “Study on the microstructure and electrochemical properties of lead-calcium-tin-aluminum alloys,”J. Power Sources, 191, Is. 1, 111-118 (2009). https://doi.org/10.1016/j.jpowsour.2008.10.059
  25. F. Tariq, S.U. Azher, and N. Naz, “Failure analysis of cast lead-antimony battery grids,” J. Fail. Anal. and Preven., 10, Is. 2, 152-160 (2010). https://doi.org/10.1007/s11668-010-9331-1
  26. I. M. Spiridonova, E. V. Sukhovaya, V. F. Butenko, А. P. Zhudra, А. I. Litvinenko, and А. I. Belyi, “Structure and properties of boron-bearing iron granules for composites,” Powder Metall. Met. Ceram., 32, Is. 2, 139-141 (1993). https://doi.org/10.1007/BF00560039
  27. B. Trembach, I. Trembach, V. Maliuha, S. Knyazev, O. Kabatskyi, O. Balenko, Y. Zarichniak, M. Brechka, M. Bodak, S. Khabosha, and H. Kniazieva, “Study of self-shielded flux-cored wire with exothermic additions CuO-Al on weld bead morphology, microstructure, and mechanical properties,” Int. J. Adv. Manuf. Technol., 137, 4685-4711 (2025). https://doi.org/10.1007/s00170-025-15414-0
  28. O.V. Sukhova, “Structure and properties of Fe-B-C powders alloyed with Cr, V, Mo or Nb for plasma-sprayed coatings,” Probl. At. Sci. Technol., 128, Is. 4, 77-83 (2020). https://doi.org/10.46813/2020-128-077
  29. A. Vashchenko, I. Spiridonova, and E. Sukhovaya, “Deformation and fracture of structural materials under high-rate strain,” [in Russian], Metalurgija, 39, Is. 2, 89-92 (2000).
  30. I.M. Spiridonova, E.V. Sukhovaya , and V.P. Balakin, “Structure and deformation peculiarities of Fe(B, C) crystals,” [in Russian], Metalurgija, 35, Is. 2, 65-67 (1996).
  31. A. Alagheband, M. Azimi, H. Hashemi, M. Kalani, and D. Nakhaie, “Optimization of grid configuration by investigating its effect on positive plate of lead acid batteries via numerical modelling,” J. Energy Storage, 12, Iss. 1-2, 202-214. (2017) https://doi.org/10.1016/j.est.2017.04.012
  32. V.L. Kulakov, Yu.M. Tarnopol’skii, A.K. Arnautov, and J. Rytter, “Stress-strain state in the zone of load transfer in a composite specimen under uniaxial tension,” Mech. Compos. Mater., 40, Is. 2, 145-160 (2004). https://doi.org/10.1023/B:MOCM.0000025483.37317.e2
  33. J. Grydzhuk, I. Chudyk, O. Slabyi, Yu. Mosora, M. Kovbaniuk, and M. Krynke, “Mathematical modeling of the stress-strain state of the annular preventer seal using the theory of reinforced shells,” Prod. Eng. Arch, 28, Is. 4, 375-380 (2022). https://doi.org/10.30657/pea.2022.28.46
  34. R.I. Sivak, L.K. Polishchuk, and G. Xianan, “Modeling of mechanical characteristics of copper-based powder materials under their plastic forming to control porosity,” Mater. Sci., 61, Is. 2, 156-164 (2025). https://doi.org/10.1007/s11003-025-00974-z
  35. N.D. Vaysfeld, and Z.Yu. Zhuravlova, “Modelling of the poroelastic state of a cuboidal reservoir,” [in Ukrainian], Fizyko-Khimichna Mekhanika Materialiv, Is. 4, 46-52 (2025). https://doi.org/10.1007/s11003-026-01014-0
  36. J.S. Musayev, T.O. Chigambaev, Y.B. Kaliyev, B.T. Kopenov, M.Zh. Turkebayev, M.A. Nartov, and A. Zhauyt, “Study on stress-strain state and deformations occurring in existing roller tables,” [in Russian], Metalurgija, 59, Is. 3, 340-342 (2020).