Kinetic features of platinum nanoparticles formation on silicon surface by galvanic replacement in DMSO environment

Keywords

platinum nanoparticles, galvanic replacement, silicon, kinetic modeling.

Cite as

Kytsya A. R., Shepida M. V., Bazylyak L. I., Holovchuk M. Ya., and Kuntyi O. I. Kinetic features of platinum nanoparticles formation on silicon surface by galvanic replacement in DMSO environment. Physicochemical Mechanics of Materials. 2024. 60(5), 085-092.

https://doi.org/10.15407/pcmm2024.05.085

Abstract

The kinetics of platinum nanoparticles formation by galvanic replacement of H₂[PtCl₆] on the silicon surface in an aprotic solvent was investigated using the methods of spectrophotometry and scanning electron microscopy. For a quantitative description of the scheme of formation of platinum nanoparticles the principles of “lump” modeling were proposed. It was shown that the minimally sufficient kinetic scheme of the process, which satisfactorily agrees with the experimental data, includes 4 intermediates and 4 pseudo-elementary stages. Numerical values of the effective rate constants of the pseudo-elementary reactions of the formation of platinum nanoparticles were calculated using mathematical modeling methods.

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