ISSN 3041-1815. Physicochemical Mechanics of Materials. 2026.
Volume 62, Issue 2

Modification of hypereutectic silumine by melt flow treatment with pulse electric current

Keywords

hypereutectic silumins, melt, structure, electric current, modification.

Cite as

Prygunova A. G., Petrov S. S., Koshelev M. V., Prygunov S. V., Zhydkov E. A., and Babiuk V. D. Modification of hypereutectic silumine by melt flow treatement with pulse electric current. Physicochemical Mechanics of Materials. 2026. 62(2), 114-121.

https://doi.org/10.15407/pcmm2026.02.114

Abstract

The features of modification of the hypereutectic Al–16.5 wt% Si alloy by treating the melt flow with a unipolar pulsed electric current of different density (j = 20–100 A/cm2) and frequency (f = 50–50000 Hz) were investigated. It was shown that the dispersion of structural components and impact toughness depend on the electric current modes and are described by the dependences that have extrema at f = 1000 Hz. With optimal processing parameters (j = 20 A/cm2, f = 1000 Hz) and a cooling rate of 2°C/s, the size of the primary silicon particles decrease twice, while the branching of the Al–Si eutectic increases in more than 3 times. The structure becomes more homogeneous, pseudo-primary dendrites of the aluminium solid solution and silicon of a new modification (Siv) appear. The aluminium microhardness of the primary silicon crystals is almost halved with a proportional increase in the microhardness. Structural and phase transformations caused by such treatment provided an increase in the impact toughness of the alloy in more than 2.5 times, which indicates the prospects for using the proposed modification method in production.

References

  1. F. Alshmri, H.V. Atkinson, S.V. Hainsworth, C. Haidon, and S.D.A. Lawe, “Dry sliding wear of aluminium-high silicon hypereutectic alloys,” Wear, 313, Is. 1-2, 106-116 (2014). https://doi.org/10.1016/j.wear.2014.02.010
  2. Z. Cai, R. Wang, C. Zhang, and C. Peng, “Characterization of rapidly solidified Al-27Si hypereutectic alloy: Effect of solidification condition,” J. Mater. Eng. Perform., 24, Is. 3, 1223-1236 (2015). https://doi.org/10.1007/s11665-015-1386-4
  3. H.S. Kang, W.Y. Yoon, K.H. Kim, and M.H.Y.P. Yoon, “Microstructure selections in the undercooled hypereutectic Al-Si alloys,” Mater. Sci. Eng., 404, Is. 1-2, 117-123 (2005). https://doi.org/10.1016/j.msea.2005.05.041
  4. M. Okayasu, S. Takeuchi, and T. Shiraishi, “Crystallisation characteristics of primary silicon particles in cast hypereutectic Al-Si alloy,” Int. J. Cast Met. Res., 26, Is. 2, 105-113 (2013). https://doi.org/10.1179/1743133612Y.0000000040
  5. L. Lasa, “Wear behaviour of eutectic and hypereutectic Al-Si-Cu-Mg casting alloys tested against a composite brake pad,” Mater. Sci. Eng. А, 363, 193-202 (2003). https://doi.org/10.1016/S0921-5093(03)00633-6
  6. W. Aiqin, Z. Lijun, and J. Խ, “Effects of cerium and phosphorus on microstructures and properties of hypereutectic Al-21% Si alloy,” J. Rare Earths, 31, Is. 5, 522-525 (2013). https://doi.org/10.1016/S1002-0721(12)60313-5
  7. T.M. Chandrashekharaiah, and S.A. Kori, “Effect of grain refinement and modification on the dry sliding wear behaviour of eutectic Al-Si alloys,” Tribol. Int., 42, Is. 1, 59-65 (2009). https://doi.org/10.1016/j.triboint.2008.05.012
  8. S.A. Kori, and T.M. Chandrashekharaiah, “Studies on the dry sliding wear behaviour of hypoeutectic and eutectic Al-Si alloys,” Wear, 263, Is. 1, 745-755 (2007). https://doi.org/10.1016/j.wear.2006.11.026
  9. Lijia He, Jianzhong Wang, Jingang Qi, Huiling Du, Xingjiang Liu, and Bing Wang, “Influences of acting parameters of electric pulse modification on the Al-22%Si-1.5%Cu alloy,” Adv. Mater. Res., 299-300, 233-237 (2011). https://doi.org/10.4028/www.scientific.net/AMR.299-300.233
  10. B.K. Prasad, K. Venkateswarlu, O.P. Modi, A.K. Jha, S. Das, and R.A.H. Dasgupta, “Sliding wear behavior of some Al-Si alloys: Role of shape and size of Si particles and test conditions,” Metall. Mater. Trans., 29, Is. 11, 2747-2752 (1998). https://doi.org/10.1007/s11661-998-0315-7
  11. K.G. Kumar Basava, “Influence of refinement and modification on dry sliding wear behavior of hypereutectic Al-Si cast alloys,” Adv. Mater. Res., 685, 112-116 (2013). https://doi.org/10.4028/www.scientific.net/AMR.685.112
  12. S. Bhattacharya, andA.T. Alpas, “Role of sliding-induced tribofilms on fracture of particles in aluminium – silicon alloys,” Wear, 301, Is. 1-2, 707-716 (2013). https://doi.org/10.1016/j.wear.2013.01.081
  13. C. Gong, H. Tu, C. Wu, Jianhua Wang,and Xuping Su, “Study on microstructure and mechanical properties of hypereutectic Al-18Si alloy modified with Al-3B,” Materials, 11, 456-467 (2018). https://doi.org/10.3390/ma11030456
  14. G.H. Qi, “A high effective and low-cost modifier for hypereutectic Al-Si alloys,” Adv. Mater., 721, 282-286 (2013). https://doi.org/10.4028/www.scientific.net/AMR.721.282
  15. Z. Min, J. Kun, and L. Xiangfa, “Refinement of hypereutectic Al-Si alloy by a new Al-Zr-P master alloy,” J. Alloys Compounds, 503, Is. 2, 26-30 (2010). https://doi.org/10.1016/j.jallcom.2010.05.017
  16. B. Ganiger, and T.M. Chandrashekharaiah, T.B. Prasad, “Modification performance of the Cu-P master alloy on commercial hypereutectic Al-24Si-Cu-Mg alloy,” Int. J. Eng. Res. Manag. Stud., 50, Is. 2, 46-50 (2017).
  17. J. Piatkowski, “AlSi17Cu5Mg alloy as future material for castings of pistons for internal combustion engines,” Metalurgija, 3, 511-514 (2015).
  18. A.S. Alghamdi, M. Ramadan, K.S. Halim, and N. Fathy, “Microscopical characterization of cast hypereutectic Al-Si alloys reinforced with graphene nanosheets,” Eng. Tech. Appl. Sci. Res., 8, Is. 1, 2514-2519 (2018). https://doi.org/10.48084/etasr.1795
  19. C.Y. Hee, J.M. Lee, W.H. Yoon, and J.G. Jung, “Influence of ultrasonic treatment on the microstructure of hypereutectic Al-17 wt.%Si alloys,” Mater. Sci. Forum, 794-796, 89-94 (2014). https://doi.org/10.4028/www.scientific.net/MSF.794-796.89
  20. K. Matsuura, M. Kudoh, H. Kinoshita, and H. Takahashi, “Precipitation of Si particles in a super-rapidly solidified Al-Si hypereutectic alloy,” Mater. Chem. Phys., 81, 393-395 (2003). https://doi.org/10.1016/S0254-0584(03)00030-0
  21. T.V.S. Reddy, D.K. Dwivedi, N.K. Jain, “Adhesive wear of stir cast hypereutectic Al-Si-Mg alloy under reciprocating sliding conditions,” Wear, 266, 1-5 (2009). https://doi.org/10.1016/j.wear.2008.05.003
  22. Yu.N. Taran, A.G. Prygunova, I.Ye. Razamirova, I.L. Belkov, S.S. Petrov, and Vaisman, “Influence of electric current treatment of the melt on the morphology of phases in complex-alloyed silumins,” Metallurgiya i Koksokhimiya [in Russian], Is. 92, 67-70 (1987).
  23. A.V. Ivanov, and V.N. Tsurkin, “Peculiarities of distribution of electromagnetic and hydrodynamic fields for conductive electric current treatment of melts in different modes,” Surf. Eng. Appl. Electrochem., 55, 53-64 (2019). https://doi.org/10.3103/S1068375519010101
  24. A.G. Prigunova, M.V. Koshelev, A.G. Borisov, “Primary silicon formation in hypereutectic alloy Al-16.5% wt. Si treated in the liquid state by a changing unipolar pulsed electric current,” Mater. Sci. and Technol., 2, Is. 1, 68-78 (2026). https://doi.org/10.1177/02670836241289037
  25. A. Szaraz, R. Pastircak, and A. Sladek, “The influence of electrical current on Al-Si alloys crystallization,” Archives of Foundry Eng., 8, Is. 2, 133-136 (2008).
  26. C.Y. Ban, Y. Han, Q.X. Ba, and J.Z. Cui, “Influence of pulse electric current on solidification structures of Al-Si alloys,” Mater. Sci. Forum, 546-549, 723-728 (2007). https://doi.org/10.4028/www.scientific.net/MSF.546-549.723
  27. V.N. Tsurkin, A.V. Ivanov, N.A. Fedchenko, S.S. Cherepovskyi, N.A. Vasyanovych, and M.L. Feshchuk, “Conductive electric current processing of the A390 alloy melt,” Protsessy Litya [in Russian], 108, Is. 6, 33-41 (2014).
  28. Zuo-fu Zhao, Jian-zhong Wang, Jin-gang Qi, Shan Dai, and Dong-jun Zhang, “Study on the influence of different pulse temperatures on Al-22% Si alloy solidification structure,” Adv. Mater. Res., 299-300, 566-571 (2011). https://doi.org/10.4028/www.scientific.net/AMR.299-300.566
  29. Xi-bin Li, Feng-gui Lu, Hai-chao Cui, and Xin-hua Tang, “Migration behavior of solidification nuclei in pure Al melt under effect of electric current pulse,” Trans. Nonferrous Met. Soc. Chin., 24, 192-198 (2014). https://doi.org/10.1016/S1003-6326(14)63047-8
  30. A.J. Plotkowski, Refinement of the Cast MicrostructureoOf Hypereutectic Aluminum-Silicon Alloys with an Applied Electric Potential, Masters Theses, Grand Valley State University (2012).
  31. A.D. Podoltsev, and I.D. Kucheryavaya, Elements of the Theory and Numerical Calculation of Electromagnetic Processes in Conductive Environments [in Russian], Instytut Elektrodynamiky Publ. House, Kyiv (1999).
  32. A.V. Ivanov, “Distribution features of electromagnetic and hydrodynamic fields in the conductive electric-current treatment of melts using parallel electrodes,” Surf. Engin. Appl. Electrochem., 56, Is. 3, 327-333 (2020). https://doi.org/10.3103/S1068375520030072
  33. Shu-xian He, Jun Wang, Wan Jiang, Bao-de Sun, and Yao-he Zhou, “Effect of melt pulse electric current and thermal treatment on A356 alloy,” Trans. Nonferrouse Met. Soc. China, 13, Is. 3, 126-130 (2003).
  34. S.S. Petrov, S.V. Prygunova, A.G. Prygunov, and D.N. Klyuchnik, Silumin Production Method [in Ukrainian], Patent of Ukraine. Publ. 11.03.2013, Bull No. 5. https://sis.nipo.gov.ua/uk/search/detail/1276480/
  35. S.A. Saltykov, Stereometric Metallography [in Russian], Metallurgiya, Moscow (1976).
  36. A.G. Prygunova, G.M. Zelinskaya, and M.V. Koshelev, “Influence of melt treatment with a unipolar pulse electric current on the formation of iron-containing phases in the AK5M2 alloy,” Metallofizika i Noveishie Tekhnologii [in Ukrainian], 41, Is. 5, 571-588 (2019). https://doi.org/10.15407/mfint.41.05.0655
  37. A.G. Prygunova, “Phase transformations during the AK7 alloy crystallization, neutralization of the harmful influence of iron by treating the melt with pulsed electric current,” Metaloznavsto ta Obrobka Metaliv [in Ukrainian], Is. 4, 17-29 (2020). https://doi.org/10.15407/mom2020.04.017
  38. A.G. Prigunova, M.V. Koshelev, and A.G. Borisov, “Effect of unipolar pulsed electric current treatment of the melt of Al-8 wt.% Si-0,7 wt.% Fe alloy on iron-containing phases formation and mechanical properties of castings,” Mater. Sci. Technol., 38, Is. 4, 246-253 (2022). https://doi.org/10.1080/02670836.2022.2037059
  39. E. Jones, and V. Stevanovic, “Polymorphism in elemental silicon: Probabilistic interpretation of the realizability of metastable structures,” Phys. Rev., B 96 (2017). Art. no. 184101 https://doi.org/10.1103/PhysRevB.96.184101
  40. Yu.N. Taran, A.G. Prygunova, V.P. Halchak, S.S. Petrov, and I.L. Belkov, “Influence of electric current on structural transformations in complex-alloyed aluminum-silicon melts,” Rasplavy [in Russian], 1, Is. 4, 111-116 (1987).