Peculiarities of modification of amorphous alloys surface with oligomer coatings from alcohol solutions

Keywords

amorphous alloys, modification, oligoperoxide coatings, corrosion resistan­ce, electrochemical characteristics.

Cite as

Hertsyk О. М., Izhyk О. В., Yezerska O. A., Kovbuz М. О., Holovchuk M. Ya., Eliyashevskyy Yu. І., and Tashak M. S. Peculiarities of modification of amorphous alloys surface with oligomer coatings from alcohol solutions. Physicochemical Mechanics of Materials. 2023. 59(6), 022-027.

https://doi.org/10.15407/pcmm2023.06.022

Abstract

The modification of the contact and outer surfaces of strip amorphous alloys Fe_78.5Ni_1.0Mo_0.5Si_6.0B_14.0 and Fe_73.1Cu_1.0Nb_3.0Si_15.5B_7.4 with 1% solutions of oligoperoxides based on vinyl acetate,
2-tert-butylperoxy-2-methyl-5-hexen-3-ine (VEP), maleic anhydride and n-vinyl pyrrolido­ne, VEP and 2-phosphonooxy ethyl 2-methacrylate in isopropyl alcohol was investigated by the methods of voltammetry, impedance spectroscopy, scanning electron and atomic force microscopy. The formation of denser coatings on the surface of the Fe_78.5Ni_1.0Mo_0.5Si_6.0B_14.0 strip and the smoothing of its topography due to the local adsorption of macromolecules of oligoperoxides were established.

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