ISSN 3041-1815. Physicochemical Mechanics of Materials. 2026.
Volume 62, Issue 1
Protection of bridge steel structures: modern approaches
Keywords
corrosion protection, hot-dip galvanizing, steel bridge structures, polari¬zation dependences, Fe–Zn intermetallic phases, corrosion potential.
Cite as
Nenastina Т. O., Berezhna K. V., and Sakhnenko M. D. Protection of bridge steel structures: modern approaches . Physicochemical Mechanics of Materials. 2026. 62(1), 138-146.
https://doi.org/10.15407/pcmm2026.01.138
Abstract
The pressing problem of ensuring the life of steel bridge structures, which has become especially critical in wartime in Ukraine due to the strategic importance of maintaining transportation infrastructure, is considered. Particular attention is paid to protecting steel bridge components against corrosion. Modern approaches to corrosion protection are analyzed, including hot-dip galvanizing, duplex systems, thermal spraying, polymer, and nanocoatings. Hot-dip galvanizing is highlighted as one of the most effective methods, forming a multilayer diffusion coating composed of intermetallic Fe–Zn phases. The structure of the coating: including γ-, δ-, ζ-, and η-phases, which provide a barrier in aggressive environments, is described. Results of experimental polarization studies in a model neutral medium (3% NaCl) confirm the protective performance of zinc coatings. Corrosion potentials and corrosion current densities for 15KhSND steel and zinc are presented. It is demonstrated that hot-dip galvanizing enables an optimal long-term protection strategy for bridge structures, combining high efficiency, economic viability, and environmental safety. The obtained results are important for the design, repair, and maintenance of bridge infrastructure.
References
- K. Medvediev, A. Kharchenko, A. Stakhova, Y. Yevseichyk, V. Tsybulskyi, and A. Bek, “Methodology for assessing the technical condition and durability of bridge structures,” Infrastructures, 9, Is. 1 (2024). Art. no. 16. https://doi.org/10.3390/infrastructures9010016
- , “Problems of functioning of transport infrastructure and logistics of Ukraine in wartime conditions,” Regional Economy, 104, Is. 2, 85-93 (2022). https://doi.org/10.36818/1562-0905-2022-2-9
- V.Yu. Salo, and O.Yu. Salo, “Operational condition of span structures of existing metal bridges on highways in the Western regions of Ukraine,” Visnyk Natsionalnogo Universytetu “Lvivska Politekcnika. Ser. Teoriya i Practyka Budivnytstva, 904, Is. 2, 50-54 (2018).
- N. Kopiika, Sa. Mitouli, and J. Ninic, “Resilience framework for aged bridges subjected to human-induced hazard – case study in Ukraine” in 4th Int. Conf. “Coordinating Engineering for Sustainability and Resilience” & Midterm Conf. of CircularB “Implementation of Circular Economy in the Built Environment”, 489, 50-62 (2024). https://doi.org/10.1007/978-3-031-57800-7_4
- M. Ved’, N. Sakhnenko, T. Nenastina, M. Volobuyev, and I. Yermolenko, “Corrosion and mechanical properties of nanostructure electrolytic Co-W and Fe-Co-W alloys,” Materials Today: Proc., 50, Is. 4, 463-469 (2022). https://doi.org/10.1016/j.matpr.2021.11.293
- Т.О. Nenastina, M.V. Ved, M.D. Sakhnenko, V.О. Proskurina, and S.І. Zyubanova, “Corrosion resistance of composite coatings based on the alloys of cobalt with refractory metals,” Mater. Sci. 56, Is. 5, 634-641 (2021). https://doi.org/10.1007/s11003-021-00475-9
- T.O. Nenastina, K.V. Berezhna, M.D. Sakhnenko, and S.O. Buhaievskyi, “Degradation of reinforced concrete construction of bridge structures: corrosion aspect,” Mater. Sci., 59, Is. 5, 538-545 (2024). https://doi.org/10.1007/s11003-024-00809-3
- P. Pokorny, J. Kolisko, L. Balik, and P. Novak, “Description of structure of Fe-Zn intermetalic compounds present in hot-dip galvanized coatings on steel,” [in Russian] Metalurgija, 54, Is. 4, 707-710 (2015).
- M. Suliga, R. Wartacz, and M. Hawryluk, “Evolution of zinc coatings during drawing process of steel wires,” Archives of Civil and Mechanical Engineering, 23 (2023). Art. no. 120. https://doi.org/10.1007/s43452-023-00669-9
- Zhiwei Li, Dingding Li, Yulong Zhou, Haoping Peng, Aijun Xie, Jianhua Wang, “A review of physical properties of hot-dip galvanized coating layer by layer and their respective electrochemical corrosion behavior,” Anti-Corrosion Methods and Materials, 71, Is. 5, 580-589 (2024). https://doi.org/10.1108/ACMM-02-2024-2963
- J.D. Culcasi, P.R. Seré, C.I. Elsner, and A.R. Sarli, “Control of the growth of zinc-iron phases in the hot-dip galvanizing process,” Surf. and Coat. Technol., 122, Is. 1, 21-23 (1999). https://doi.org/10.1016/S0257-8972(99)00404-1
- M. Šmak, Ja. Kubicek, Ji. Kala, and Ja. Vanerek, “The influence of hot-dip galvanizing on the mechanical properties of high-strength steels,” Materials, 14, Is. 18 (2021). Art. no. 5219. https://doi.org/10.3390/ma14185219
- DSTU ISO 12944-4:2019. “Paints and Varnishes. Corrosion Protection of Steel Structures with Protective Paint Systems. Part 4. Surface Types and their Preparation,” (ISO 12944-4:2017, IDT)
- S.I. Ryabtsev, V.A. Polonskyi, and O.V. Sukhova, “Structure and corrosion of quasicrystalline cast alloys and Al-Cu-Fe film coatings,” Mater. Sci., 56, Is. 2, 263-272 (2020). https://doi.org/10.1007/s11003-020-00428-8
- M.V. Ved’, T.O. Nenastina, V.V. Shtefan, T.M. Bairachna, and M.D. Sakhnenko, “Corrosion and electrochemical properties of binary cobalt and nickel alloys,” Mater. Sci., 44, Is. 6, 840-843 (2008). https://doi.org/10.1007/s11003-009-9141-3
- А.О. Mazeilis, І.О. Patsai, “Using the MTech PGP-550S potentiostat function of nonlinear polarization based on given data,” in Electrokcimiya Syogodennya: Zdobutky, Problemy ta Perspektyvy [in Ukrainian], Gordon, Kyiv (2021), pp. 88-89.
- M.V. Ved’, N.D. Sakhnenko, I.Y. Yermolenko, and T.A. Nenastina, “Nanostructured functional coatings of iron family metals with refractory elements,” in Proc. 5th Int. Conf. Nanotechnology and Nanomaterials (NANO 2017). Springer Proceedings in Physics, 214 (2018), pp. 3-34. https://doi.org/10.1007/978-3-319-92567-7_1
- L. Paterlini, A. Brenna, F. Ceriani, M. Gamba, M. Ormellese, and F. Bolzoni, “Atmospheric corrosion of different steel types in urban and marine exposure,” Materials (Basel), 17, Is. 24 (2024. ). Art. no. 6211. https://doi.org/10.3390/ma17246211
- Ni. Weiliang, Li. Peng, Zhu Yajun, Di Zhigang, Guo Liangliang, and L. Yunqi, “Comparative study of anti-corrosion properties and lifespan prediction model for inorganic zinc-rich coating and thermal-spray zinc coating,” Coatings, 12, Is. 4 (2022). Art. no. 505. https://doi.org/10.3390/coatings12040505
- Z. Yu, S. Zhang, and J. Chen, “A review of recent developments in coating systems for hot-dip galvanized steel,” Frontiers in Materials, 7 (2020). Art. no. 74. https://doi.org/10.3389/fmats.2020.00074
- Die Wang, Zhiyue Gao, Yaping Wu, Baoshuai Du, and Zhibin Fan, “Selection of zinc coatings based on corrosion behavior and environmental impact assessment,” Coatings, 15, Is. 2 (2025). Art. no. 199. https://doi.org/10.3390/coatings15020199
- Han-Seung Lee, Jitendra Kumar Singh, Mohamed A. Ismail, Chinmoy Bhattacharya, Asiful H. Seikh, Nabeel Alharthi, and Raja Rizwan Hussain, “Corrosion mechanism and kinetics of Al-Zn coating deposited by arc thermal spraying process in saline solution at prolong exposure periods,” Scientific Reports, 9 (2019). Art. no. 3399. https://doi.org/10.1038/s41598-019-39943-3
- M. van Leeuwen, F.E. Goodwin, M. Gagné, “When good is not good enough – synergistic effects of duplex coatings result in extreme durability,” Asia Pacific General Galvanizing Conf., 10, Is. 4, 12-17 (2019).