ISSN 0430-6252. Physicochemical Mechanics of Materials. 2023.
Volume 59, Issue 4

Structure and properties of polyester composites with polymer silicate modifier

Keywords

modifier, polyvinylpyrrolidone, hardening, intermolecular interaction, struc­ture, spectroscopic studies, polyester compositions, silicate fillers.

Cite as

Masiuk A. S., Bilyi L. M., Humenetskyi P. V., Levytskyi V. Ye., and Humenetskyi T. V. Structure and properties of polyester composites with polymer silicate modifier. Physicochemical Mechanics of Materials. 2023. 59(4), 123-128.

https://doi.org/10.15407/pcmm2023.04.123

Abstract

The effect of metal-containing polymer silicate modifiers on the regularities of hardening and properties of polyester composites was studied. The effect of the nature, concentration, and method of introduction of the modifier component (polyvinyl alcohol and polyvinyl­pyrrolidone) and the nature of the metal on the surface characteristics of metal-containing polymer silicate materials was determined. It was found that intermolecular interactions of active silicate and functional groups of the high-molecular component occur during such materials production.

References

  1. V. K. Thakur, M. K. Thakur, and A. Pappu, Hybrid Polymer Composite Materials: Properties and Characterization, Woodhead Publ. & Elsevier, Cambridge (2017).
  2. M. Mishra (Ed.), Encyclopedia of Polymer Applications, Boca Raton: CRC Press., London; New York Publ. (2018).
  3. V. Levytskyi, D. Katruk, A. Masyuk, T. Bialopiotrowicz, M. Bratychak, and N. Chopyk, “The effect of poly(vinyl chloride) modifier and filler nature on properties of polyester composites,” Chemistry and Chemical Techn., 12, Is. 1, 53-57 (2018). https://doi.org/10.23939/chcht12.01.053
  4. M. García, Polymer-Inorganic Nanocomposites Influence of Colloidal Silica, Thesis University of Twente (2004).
  5. Y.-W. Mai, and Z.-Z. Yu, Polymer Nanocomposites, Woodhead Publ. Lim., Cambridge (2006).
  6. R. K. Gupta, E. Kennel, & K.-J. Kim (Eds.)., Polymer Nanocomposites Handbook, CRC Press, Cambridge (2009). https://doi.org/10.1201/9781420009804
  7. V. Mittal (Ed.), Polymer Nanocomposites: Advances in Filler Surface Modification Technique, Nova Sci. Publ., New York (2009).
  8. M. Xantos (Ed.), Functional Fillers for Plastics, Wiley-VCH Verlag GmbH & Co. KGaA (2010).
  9. V. Levytskyi, A. Masyuk, T. Bialopiotrowicz, L. Bilyi, and T. Humenetskyi, “Morphology and properties of thermoplastic composites with modified silicate fillers,” Mater. Sci., 54, No. 1, 48-54 (2018). https://doi.org/10.1007/s11003-018-0157-4
  10. V. Levytskyi, A. Masyuk, D. Samoiliuk, L. Bilyi, and T. Humenetskyi, “Morphology and properties of polymer-silicate composites and polyester materials based on them,” Mater. Sci., 52, No. 1, 17-24 (2016). https://doi.org/10.1007/s11003-016-9921-5
  11. D. Mondal, Md. M. R. Mollick, B. Bhowmick, D. Maity, M. K. Bain, D. Rana, A. Mukhopadhyay, K. Dana, and D. Chattopadhyay, “Effect of poly(vinylpyrrolidone) on the morphology and physical properties of poly(vinyl alcohol)/sodium montmorillonite nanocomposite films,” Progress in Natural Sci.: Mat. Int., 23, Is. 6, 579-587 (2013). https://doi.org/10.1016/j.pnsc.2013.11.009
  12. V. Levytskyi, A. Masyuk, L. Bilyi, T. Bialopiotrowicz, T. Humenetskyi, ana A. Shybanova, “Influence of silicate nucleation agent modified with polyvinylpyrrolidone on the morphology and properties of polypropylene,” Mater. Sci., 55, No. 4, 555-562 (2020). https://doi.org/10.1007/s11003-020-00338-9
  13. U. Poth (Ed.), Polyester und Alkydharze, Vincentz Network, Germany: Publ. (2014).
  14. D. Katruk, V. Levytskyi, U. Khromyak, V. Moravskyi, and A. Masyuk, “Physicochemical principles of synthesis and modification of unsaturated polyester-polyvinyl chloride composites and the properties of materials derived from them,” Int. J. of Polymer Sci., 2019, art. ID 2547384 (2019). https://doi.org/10.1155/2019/2547384
  15. V. Chaudhary, A. K. Rajput, and P. K. Bajpai, “Effect of particulate filler on mechanical properties of polyester based composites,” Materials Today: Proc., 4, Is. 9, 9893-9897 (2017). https://doi.org/10.1016/j.matpr.2017.06.289
  16. V. Mittal (Ed.), Functional Polymer Blends: Synthesis, Properties, and Performance, Boca Raton: CRC Press., London; New York Publ. (2012). https://doi.org/10.1201/b11799-2
  17. Y. Gao, P. Romero, H. Zhang, M. Huang, and F. Lai, “Unsaturated polyester resin concrete: A review,” Construction and Building Mat., 228, art. no. 116709 (2019). https://doi.org/10.1016/j.conbuildmat.2019.116709
  18. F. Chu, X. Yu, Y. Hou, X. Mu, L. Song, and W. Hu, “A facile strategy to simultaneously improve the mechanical and fire safety properties of ramie fabric-reinforced unsaturated polyester resin composites,” Composites Part A: Appl. Sci. and Manufact., 115, 264-273 (2018). https://doi.org/10.1016/j.compositesa.2018.10.006
  19. V. Skorokhoda, Y. Melnyk, N. Semenyuk, and O. Suberlyak, “Obtaining peculiarities and properties of polyvinylpyrrolidone copolymers with hydrophobic vinyl monomers,” Chemistry & Chemical Techn., 9, Is. 1, 55-59 (2015). https://doi.org/10.23939/chcht09.01.055
  20. Y. Melnyk, Y. Stetsyshyn, V. Skorokhoda, and Y. Nastishin, “Polyvinylpyrrolidone-graft-poly(2-hydroxyethylmethacrylate) hydrogel membranes for encapsulated forms of drugs,” J. of Polymer Res., 27, Is. 11, 1-11 (2020). https://doi.org/10.1007/s10965-020-02335-7
  21. M. B. Roller, “Rheology of curing thermosets: a review,” Polymer Eng. and Sci., 26, Is. 6, 432-440 (1986). https://doi.org/10.1002/pen.760260610
  22. V. Levytskyi, A. Masyuk, D. Katruk, and M. Bratychak, “Regularities of obtaining, morphology and properties of metal-containing polymer-silicate materials and polyester composites on their basis,” Chemistry & Chemical Techn., 10, No. 1, 35-40 (2016). https://doi.org/10.23939/chcht10.01.035