Synthesis and catalytic properties of Ag(Pd) bimetallic nanoparticles

Keywords

bimetallic nanoparticles, silver, palladium, aerobic oxidation, benzyl alcohol.

Cite as

Bazyliak L. I., Sheparovych R. B., Liutyi P. Ya., Shepida M. V., Kuntyi O. I., and Kytsia A. R. Synthesis and catalytic properties of Ag(Pd) bimetallic nanoparticles. Physico­chemical Mechanics of Materials. 2023. 59(6), 124-130.

https://doi.org/10.15407/pcmm2023.06.124

Abstract

Ag(Pd) bimetallic nanostructures (Ag(Pd)NPs) were synthesized by the method of galvanic replacement of palladium ions with silver nanoparticles. On the basis of a comparative analysis of the results of scanning electron microscopy, energy dispersive X-ray micro­analysis and X-ray powder diffraction, it was established that the obtained Ag(Pd)NPs can be considered as “core-shell” nanosystems, in which the core is silver, and the shells are palladium nanoparticles with a size of 5–15 nm. Ag(Pd)NPs were studied as catalysts for the aerobic liquid-phase oxidation of benzyl alcohol. It was shown that the addition of Ag(Pd)NPs to the reaction system accelerates the reaction in 14 times

References

1. M. J. Ndolomingo, N. Bingwa, and R. Meijboom, “Review of supported metal nanoparticles: synthesis methodologies, advantages and application as catalysts,” J. Mater. Sci., 55, Is. 15, 6195-6241 (2020). https://doi.org/10.1007/s10853-020-04415-x
2. I. A. Opeida, A. R. Kytsya, L. I. Bazylyak, and O. I. Pobigun, “Silver nanoparticle catalysis of the liquid-phase radical chain oxidation of cumene by molecular oxygen,” Theor. Exp. Chem., 52, Is. 6, 369-374 (2017). https://doi.org/10.1007/s11237-017-9492-z
3. I. A. Opeida, A. R. Kytsya, L. I. Bazylyak, and O. I. Pobigun-Halaiska, “Magnetically separable nanocatalyst ag@ni for the liquid-phase oxidation of cumene,” Theor. Exp. Chem., 54, Is. 4, 242-246 (2018). https://doi.org/10.1007/s11237-018-9569-3
4. N. Mimura, N. Hiyoshi, T. Fujitani, and F. Dumeignil, “Liquid phase oxidation of glycerol in batch and flow-type reactors with oxygen over Au-Pd nanoparticles stabilized in anion-exchange resin,” RSC Adv., 4, Is. 63. 33416-33423 (2014). https://doi.org/10.1039/C4RA04960H
5. T. Dang-Bao, I. Favier, and M. Gómez, “Metal nanoparticles in polyols: bottom-up and top-down syntheses and catalytic applications,” In Nanoparticles in Catalysis: Adv. in Synthesis and Appl. (2021), pp. 99-122. https://doi.org/10.1002/9783527821761.ch5
6. N. M. Bertero, A. F. Trasarti, B. Moraweck, A. Borgna, and A. J. Marchi, “Selective liquid-phase hydrogenation of citral over supported bimetallic Pt-Co catalysts,” Appl. Cat. A: General, 358, Is. 1, 32-41 (2009). https://doi.org/10.1016/j.apcata.2009.01.036
7. J. Shi, “On the synergetic catalytic effect in heterogeneous nanocomposite catalysts,” Chem. Rev., 113, Is. 3, 2139-2181 (2011). https://doi.org/10.1021/cr3002752
8. N. Dimitratos, J. A. Lopez-Sanchez, and G. J. Hutchings, “Selective liquid phase oxidation with supported metal nanoparticles,” Chem. Sci., 3, Is. 1, 20-44 (2012). https://doi.org/10.1039/C1SC00524C
9. Y. Li, L. Xiao, F. Liu, Y. Dou, S. Liu, Y. Fan, G. Cheng, W. Song, and J. Zhou, “Core-shell structure Ag/ Pd nanoparticles supported on layered MnO2 substrate as toluene oxidation catalyst,” J. Nanopart. Res., 21, Is. 2, art. no. 28 (2019). https://doi.org/10.1007/s11051-019-4467-8
10. V. V. Torbina, A. A. Vodyankin, S. Ten, G. V. Mamontov, M. A. Salaev, V. I. Sobolev, and O. V. Vodyankina, “Ag-based catalysts in heterogeneous selective oxidation of alcohols: A review,” Catalysts, 8, Is. 10, art. no. 447 (2018). https://doi.org/10.3390/catal8100447
11. S. Zaid, E. Skrzyńska, A. Addad, S. Nandi, L. Jalowiecki-Duhamel, J.-S. Girardon, M. Capron, and F. Dumeignil, “Development of silver based catalysts promoted by noble metal M (M = Au, Pd or Pt) for glycerol oxidation in liquid phase,” Top. Catal., 60, Is. 15-16, 1072-1081 (2017). https://doi.org/10.1007/s11244-017-0800-6
12. K. Kaneda, and T. Mitsudome, “Metal-support cooperative catalysts for environmentally benign molecular transformations,” Chem. Rec., 17, Is. 1, 4-26 (2017). https://doi.org/10.1002/tcr.201600036
13. E. Fisher, L. Kenisgberg, M. Carreira, J. Fernandez-Gallardo, R. Baldwin, and M. Contel, “Water-compatible gold and silver nanoparticles as catalysts for the oxidation of alkenes,” Polyhedron, 120, 82-87 (2016). https://doi.org/10.1016/j.poly.2016.06.012
14. S. Ten, V. V. Torbina, V. I. Zaikovskii, S. A. Kulinich, and O. V. Vodyankina, “Bimetallic AgPd/UiO-66 hybrid catalysts for propylene glycol oxidation into lactic acid,” Materials, 13, Is. 23, art. no. 5471, 1-18 (2020). https://doi.org/10.3390/ma13235471
15. Y. Wang, B. Wang, L. Ling, R. Zhang, and M. Fan, “Probe into the effects of surface composition and ensemble effect of active sites on the catalytic performance of C2H2 semihydrogenation over the Pd-Ag bimetallic catalysts,” Chem. Eng. Sci., 218, art. no. 115549 (2020). https://doi.org/10.1016/j.ces.2020.115549
16. V. Babel, and B. L. Hiran, “Heterogeneous AgPd alloy nanocatalyst for selective reduction of aromatic nitro compounds using formic acid as hydrogen source,” Catal. Lett., 150, Is. 7, 1865-1869 (2020). https://doi.org/10.1007/s10562-020-03098-y
17. S. Gao, T. Feng, Q. Wu, C. Feng, N. Shang, and C. Wang, “Immobilizing AgPd alloy on Vulcan XC-72 carbon: a novel catalyst for highly efficient hydrogen generation from formaldehyde aqueous solution,” RSC Adv., 6, Is. 107, 105638-105643 (2016). https://doi.org/10.1039/C6RA22761A
18. N.-Z. Shang, C. Feng, S. T. Gao, and C. Wang, “Ag/Pd nanoparticles supported on amine-functionalized metal-organic framework for catalytic hydrolysis of ammonia borane,” Int. J. Hydrog. Energy., 41, Is. 2, 944-950 (2016). https://doi.org/10.1016/j.ijhydene.2015.10.062
19. X. Zhang, N. Shang, H. Shang, T. Du, X. Zhou, C. Feng, S. Gao, C. Wang, and Z. Wang, “Nitrogen-decorated porous carbon supported aged nanoparticles for boosting hydrogen generation from formic acid,” Energy Technol., 7, Is. 1, 140-145(2019). https://doi.org/10.1002/ente.201800522
20. C. Wen, A. Yin, and W.-L. Dai, “Recent advances in silver-based heterogeneous catalysts for green chemistry processes,” Appl. Catal. B: Environmental, 160-161, Is. 1, 730-741 (2014). https://doi.org/10.1016/j.apcatb.2014.06.016
21. L. Akselrud, and Y. Grin, “WinCSD: Software package for crystallographic calculations (Version 4),” J. Appl. Crystallogr., 47, Is. 2, 803-805 (2014). https://doi.org/10.1107/S1600576714001058
22. I. A. Opeida, R. B. Sheparovych, and W. Ya. Suprun, “Kinetic analysis of aerobic oxidation catalyzed by a hybrid heterogeneous-homogeneous system containing supported Mn and V oxides and N-hydroxyphthalimide,” J. Catal., 424, 197-210 (2023). https://doi.org/10.1016/j.jcat.2023.04.016
23. G. Zozulya, O. Kuntyi, R. Mnykh, A. Kytsya, and L. Bazylyak, “Synthesis of silver nanoparticles by sonogalvanic replacement on aluminium powder in sodium polyacrylate solutions,” Ultrason. Sonochem., 84, art. no. 105951 (2022). https://doi.org/10.1016/j.ultsonch.2022.105951
24. G. I. Zozulya, O. I. Kuntyi, I. P. Mertsalo, and A. S. Mazur, “Production of Cu/Ag porous bimetal by the galvanic replacement of dezincified brass,” Mater. Sci., 56, No. 5, 668-672 (2021). https://doi.org/10.1007/s11003-021-00480-y
25. М. V. Shepida, О. І. Kuntyi, Y. V. Sukhatskyi, and M. Ya. Holovchuk, “Modification of porous silicon with palladium nanoparticles by the method of sonogalvanic replacement,” Sci., 58, No. 2. 196-200 (2022). https://doi.org/10.1007/s11003-022-00649-z
26. О. Kuntyi, G. Zozulya, and A. Kytsya, “”Green” synthesis of metallic nanoparticles by sonoelectrochemical and sonogalvanic replacement methods,” Chem. Appl., 2021, art. no. 9830644 (2021). https://doi.org/10.1155/2021/9830644
27. N. Gul, S. Ata, I. Bibi, M. Azam, A. Shahid, N. Alwadai, N. Masood, and M. Iqbal, “Size controlled synthesis of silver nanoparticles: A comparison of modified Turkevich and BRUST methods,” Zeitschrift fur Physikalische Chemie, (2022). https://doi.org/10.1515/zpch-2022-0009
28. Y. Chen, H. Wang, C. J. Liu, Z. Zeng, H. Zhang, C. Zhou, X. Ija, and Y. Yang, “Formation of monometallic Au and Pd and bimetallic Au-Pd nanoparticles confined in mesopores via Ar glow-discharge plasma reduction and their catalytic applications in aerobic oxidation of benzyl alcohol,” J. Catal., 289, 105-117 (2012). https://doi.org/10.1016/j.jcat.2012.01.020