ISSN 0430-6252. Physicochemical Mechanics of Materials. 2022.
Volume 58, Issue 2
Technology of mesostructure formation in sintered WC–Co and WC–Ni hard alloys
Keywords
sintered WC–Co, WC–Ni hard alloys, tungsten carbide, granule, mesostruc¬ture, friction pairs.
Cite as
Matviichuk О. О., Andreiev І. V., Hnatenko І. О., Ievdokymova O. V., Davydenko S. А., and Tsysar M. О. Technology of mesostructure formation in sintered WC–Co and WC–Ni hard alloys. Physicochemical Mechanics of Materials. 2022. 58(2), 029-032.
Abstract
Іt is demonstrated for the first time that the mesostructural WC–Co or WC–Ni hard alloy can be obtained by ordinary liquid-phase sintering at temperatures from 1290°C to 1370°C and isothermal holding time of 10–20 min. The hardness of the alloys with a mesostructure with a decreasing cobalt content from 28 to 20 mass%, increases from 77.5 to 81 HRA, while the microhardness of mesoelements can change from 4.76 to 6.3 GPa. The mesostructural WC–Co alloys are effective in upsetting and stamping tool and mining tool where high wear and impact resistance and load variability are required, and WC–Ni are effective when used in heavy friction pairs.
References
- A. F. Lisovsky, “Theory and practice of mesostructure formation in composite materials: A Review,” J. Superhard Mater.,42, No. 3, 129–144 (2020).
- X. Deng, D. R. Patterson, K. K. Chawla, M. Koopman, Z. F. Zhigang, G. Lockwood, and A. Griffo, “Mechanical properties of a hybrid cemented carbide composite,” Int. J. Refractory Met. Hard Mater.,19, 547–552 (2001).
- Z. Fang and J. A. Sue, “Double cemented carbide composites,” US Patent,N 5880382. Publ. (1999).
- A. F. Lisovsky, “On the imbibition of metal melts by sintered carbides,” Powder Met. Intern.,No. 5, 18–21 (1987).
- A. F. Lisovsky, “The migration of metal melts in sintered composite materials,” Int. J. Refract. Hard Metals,33, No. 8, 1599–1603 (1990).
- V. P. Bondarenko, I. O. Hnatenko, O. O. Matviychuk, M. M. Prokopiv, and V. G. Zavolokin, “Study of the relationship between the cross-sectional shape of high-temperature WC grains and their microhardness,” in: Porodorazr. Metalloobr. Instr. Tekh. Tekhnol. Izgot. Primen.,Issue 20 (2017), pp. 415–421.
- I. O. Hnatenko, Improvement of the Method for the Evaluation of the State of Carbide Skeleton of Tungsten Hard Alloys and Determination of the Influence of Technological Factors[in Ukrainian], Candidate-Degree Thesis (Engineering), Kyiv (2017).
- G. S. Kreimer, Strength of Solids[in Russian], Metallurgy, Moscow (1971).
- Y. V. Milman, “The effect of structural state and temperature on the mechanical properties and deformation mechanisms of WC–Co hard alloy,” J. Superhard Mater.,36, 65–81 (2014).
- V. P. Bondarenko, Triboengineering Composites with High Modulus Fillers[in Ukrainian], Naukova Dumka, Kyiv (1987).
- A. V. Shatov, S. S. Ponomarev, S. A. Firstov, and R. Warren, “The contiguity of carbide crystals of different shapes in cemented carbides,” Int. J. Refract. Met. Hard Mater.,24, No. 1–2, 61–74 (2006).
- A. F. Lisovsky, “Role of materials science in increasing the efficiency of a rock-crushing tool equipped with WC–Co cemented carbide inserts: A Review,” J. Superhard Mater.,42, 203–222 (2020).
- V. I. Pokhmurs’kyi, Kh. B. Vasyliv, V. A. Vynar, V. M. Dovhunyk, I. V. Koval’chuk, and O. P. Khlopyk, “Effect of alloying components on the tribocorrosion properties of tungsten-carbide cermets,” Mater. Sci.,51, No. 5, 869–876 (2016).
- V. A. Vynar, “Corrosion behavior of VN20 alloy doped with graphite or chromium and vanadium carbides,” Mater. Sci.,50, No. 5, 721–725 (2015).
- M. I. Dvornik and E. A. Mykhailenko, “Strength testing of VK8 hard alloy by the finite-element method,” Chem. Phys. Mesoscopy,11, No. 4, 433–440 (2009).
- A. M. Baranovskii and A. G. Bezruchko, “Antifriction materials based on the VN-type hard alloy and the experience of their application in heavily loaded couples of sliding friction,” Instrument. World,No. 1 (57), 12–15 (2013).