ISSN 3041-1815. Physicochemical Mechanics of Materials. 2026.
Volume 62, Issue 1
The influence of chrome and nickel in alloyed medium carbon steels on surface nanostructure formation
Keywords
surface nanocrystalline structure, alloying elements, chrome, nickel, lattice relative deformation, microhardness.
Cite as
Kyryliv V. I., Maksymiv O. V., Tsizh B. R., Kulyk Yu. O., and Kravchyshyn T. M. The influence of chrome and nickel in alloyed medium carbon steels on surface nanostructure formation. Physicochemical Mechanics of Materials. 2026. 62(1), 057-061.
https://doi.org/10.15407/pcmm2026.01.057
Abstract
The influence of chrome and nickel in medium carbon steels on formation of surface nanocrystalline structure by severe plastic deformation during mechanical-pulse treatment was studied. It was established that nickel and chrome changed structural-phase state of created nanocrystalline structure, raised the relative deformation of the lattice, dislocation density and microhardness of the surface layer. It was assumed that those available alloying elements in the steels would promote wear resistance increase of their surface nanocrystalline layers.
References
- M.S. Stechyshyn, N.M. Stechyshyna, N.S. Mashovets, D.V. Zdorenko, M.I. Tsepenyk, and V.M. Yuskiv, “Corrosion-mechanical wear of carbonitrided steel in alkaline environment,” Mater. Sci., 60, Is. 4, 536-542 (2025). https://doi.org/10.1007/s11003-025-00916-9
- V.G. Mishchenko, D.M. Tonkonoh, E.A. Bazhmina, A.O. Kharchenko, and V.V. Kornienko, “Specific features of cementation of high-chromium martensitic-ferritic 06Kh18ch steel in a pasty carburizer,” Mater. Sci. 61, Is. 2, 180-185 (2025). https://doi.org/10.1007/s11003-025-00977-w
- M. Student, I. Pohrelyuk, J. Padgurskas, R. Rukuiza, V. Hvozdetskyi, Kh. Zadorozhna, O. Student, and O. M. Tkachuk, “Abrasive wear resistance and tribological characteristics of pulsed hard anodized layers on aluminum alloy 1011 in tribocontact with steel and ceramics in various lubricants,” Coatings, 13, Is. 11. (2023). Art. no. 1883. https://doi.org/10.3390/coatings13111883
- M. Bembenek, V. Kopei, L.Y. Ropyak, and K. Levchuk, “Stressed state of chrome parts during diamond burnishing,” Metallofizika i Noveishie Tekhnologii [in Russian], 45, Is. 2, 239-250 (2023). https://doi.org/10.15407/mfint.45.02.0239
- L.Y. Ropyak, M.V. Makoviichuk, I.P. Shatskyi, I.M. Pritula, L.O. Gryn, and V.O. Belyakovskyi, “Stressed state of laminated interference-absorption filter under local loading,” Functional Mat., 27, Is. 3, 638-642 (2020). https://doi.org/10.15407/fm27.03.638
- A.I. Balitskii, A.M. Syrotyuk, M.R. Havrilyuk, V.O. Balitska, V.O. Kolesnikov, and L.M. Ivaskevych, “Hydrogen cooling of turbo aggregates and the problem of rotor shafts materials degradation evaluation,” Energies, 16, Is. 23 (2023). Art. no. 7851. https://doi.org/10.3390/en16237851
- A.I. Balitskii, M.R. Havrilyuk, V.O. Balitska, V.O. Kolesnikov, and L.M. Ivaskevych, “Increasing turbine hall safety by using fire-resistant, hydrogen-containing lubricant cooling liquid for rotor steel mechanical treatment,” Energies, 16, Is. 1 (2023). Art. no. 535. https://doi.org/10.3390/en16010535
- N.Y. Imbirovich, M.D. Klapkiv, V.M. Posuvailo, and O.Y. Povstyanoi, “Properties of ceramic oxide coatings on magnesium and titanium alloys synthesized in electrolytic plasma,” Powder Metallurgy and Metal Ceramics, 54, Iss. 1-2, 47-52 (2015). https://doi.org/10.1007/s11106-015-9678-7
- M. Student, V. Hvozdetskyi, T. Stupnytskyi, O. Student, P. Maruschak, O. Prentkovskis, and P. Skačkauskas, “Mechanical properties of arc coatings sprayed with cored wires with different charge com-positions,” Coatings, 12, Is. 7 (2022). Art. no. 925. https://doi.org/10.3390/coatings12070925
- V.M. Posuvailo, M.D. Klapkiv, M.M. Student, Y.Y. Sirak, and H.V. Pokhmurska, “Gibbs energy calculation of electrolytic plasma channel with inclusions of copper and copper oxide with Al-base,” in IOP Conf. Ser.: Mater. Sci. and Eng., 181, Is. 1 (2017) Art. no. 012045. https://doi.org/10.1088/1757-899X/181/1/012045
- N.M. Fialko, V.V. Shchepetov, and S.D. Kharchenko, “Nanostructural composite lubricant coating,” J. of KNU, Is. 6, 51-59 (2022). https://doi.org/10.31891/2079-1372-2022-106-4-6-12
- M.M. Student, V.M. Posuvailo, H.H. Veselivs’ka, Y.Y. Sirak, and R.A. Yatsyuk, “Corrosion resistance of plasma-electrolytic layers on alloys and coatings of the Al-Cu-Mg system for various modes of heat treatment,” Mater. Sci., 53, Is. 6, 789-795 (2018). https://doi.org/10.1007/s11003-018-0137-8
- I.P. Shatskyi, L.Y. Ropyak, and M.V. Makoviichuk, “Strength optimization of a two-layer coating for the particular local loading conditions,” Strength Mater., 48, Is. 5, 726-730 (2016). https://doi.org/10.1007/s11223-016-9817-5
- L. Ropyak, T. Shihab, A. Velychkovych, O. Dubei, T. Tutko, and V. Bilinskyi, “Design of a two-layer Al-Al2O3 сoating with an oxide layer formed by the plasma electrolytic oxidation of Al for the corrosion and wear protections of steel,” Progress in Physics of Metals, 24, 319-365 (2023). https://doi.org/10.15407/ufm.24.02.319
- I.E. Volokitina, A.I. Denissova, and A.V. Volokitin, “Evolution of the microstructure of steel in the processes of severe plastic deformation,” Progress in Physics of Metals, 26, 89-119 (2025). https://doi.org/10.15407/ufm.26.01.091
- D.A. Lesyk, V.V. Dzhemelinskyi, S. Martinez, B. N. Mordyuk, and A. Lamikiz, “Surface shot peening post-processing of inconel 718 alloy parts printed by laser powder bed fusion additive manufacturing,” J. of Mater. Eng. and Performance, 30, Is. 9, 6982-6995 (2021). https://doi.org/10.1007/s11665-021-06103-6
- V. Gurey and I. Hurey, “The effect of the hardened nanocrystalline surface layer on durability of guideways,” in Advanced Manufacturing Processes. Lecture Notes in Mechanical Engineering, Cham: Springer (2020), pp. 63-72. https://doi.org/10.1007/978-3-030-40724-7_7
- H. Nykyforchyn, V. Kyryliv, and O. Maksymiv, “Effect of nanostructurisation of dtructural steels on its wear resistance and hydrogeb embrittlement resistance,” Solid State Phenomena, 225, 65-70 (2015). https://doi.org/10.4028/www.scientific.net/SSP.225.65
- Y. Kyryliv, V. Kyryliv, B. Tsizh, and O. Maksymiv, “Resistance of surface nanostructures and ultrafine grain structures on steel 40Kh to wear and cavitation-erosive destruction,” Appl. Nanosci., 12, Is. 4, 1085-1090 (2022). https://doi.org/10.1007/s13204-021-01751-5
- V.I. Kyryliv, V.I. Zakiev, and O.V. Maksymiv, “Change the modulus of elesticity of the surface nanostuctured layer on U8 steel,” Mater. Sci., 58, Is. 6, 795-800 (2023). https://doi.org/10.1007/s11003-023-00732-z
- V.I. Kyryliv, B.P. Chaikovs’kyi, O.V. Maksymiv, and A.V. Shal’ko, “Contact fatigue of 20KHN3A steel with surface nanostructure,” Mater. Sci., 51, Is. 6, 833-838 (2016). https://doi.org/10.1007/s11003-016-9909-1
- C. Koch, “Optimization of strength and ductility in nanocrystalline and ultrafine grained metals,” Scripta Mat., 49, Is. 7, 657-662 (2003). https://doi.org/10.1016/S1359-6462(03)00394-4
- W. Krous, and G. Nolze, “Powder Cell – A Program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns,” J. Appl. Cryst., 29, 301-303 (1996). https://doi.org/10.1107/S0021889895014920
- Powder Diffraction File Search Manual: Alphabetical Listing and Search Section of Frequently Encountered Phases, JCPDS, Philadelphia (1974).
- V. Kyryliv, B. Chaikovs’kyi, O. Maksymiv, and B. Mykytchak, “Fatigue and corrosion fatigue of the roll steels with surface nanostructure,” J. of Nano Research, 51, 92-97 (2018). https://doi.org/10.4028/www.scientific.net/JNanoR.51.92
- E.E. Glikman and R.E. Bruver, “Equilibrium segregation at the grain boundaries and intercrystalline cold brittleness of solid solutions,” Metallofizika [in Russian], 43, 42-43 (1972).
- B.I. Kostetskyi, I.G. Nosovskyi, A.K. Karaulov, L.I. Bershadskyi, N.B. Kostetska, V.A. Lyashkov, and M.F. Sagach, Surface Strength of Materials Under Friction [in Russian], Tekhnika, Kyiv (1976).
- V.I. Kyryliv, O.V. Maksymiv, V.R. Ivashkiv, Y.O. Kulyk, B.P. Chaikovs’kyi, and I.H. Yaroshovych, Wear resistance of nanostructural layer alloyed with nickel and chrome on the steel 45 surface,” Mater. Sci., 61, Is. 3, 323-329 (2025). https://doi.org/10.1007/s11003-025-00996-7
- P. Guo, S. Ma, M. Jiao, P. Lu, J. Xing, L. Xu, and Z. Huang, “Effect of chromium on microstructure and oxidation wear behavior of high-boron high-speed steel at elevated temperatures,” Materials, 15, Is. 2 (2022) Art. no. 557. https://doi.org/10.3390/ma15020557