ISSN 3041-1815. Physicochemical Mechanics of Materials. 2025.
Volume 61, Issue 3
Wear resistance of nanostructural layer alloyed with nickel and chrome on the steel 45 surface
Keywords
steel, surface nanocrystalline structure, wear resistance, alloying, chrome, nickel, secondary structures, electrochemical potential.
Cite as
Kyryliv V. I., Maksymiv O. V., Ivashkiv V. R., Kulyk Yu. O., Chaikovskyi B. P., and Yaroshovych I. H. Wear resistance of nanostructural layer alloyed with nickel and chrome on the steel 45 surface. Physicochemical Mechanics of Materials. 2025. 61(3), 041–046.
https://doi.org/10.15407/pcmm2025.03.041
Abstract
The wear resistance of steel 45 in oil-abrasive medium with surface nanocrystalline structure formed by severe plastic deformation using energy of high-speed friction with additional alloying with chrome and nickel from special technological media during mechanical-pulse treatment is studied. The increase of the wear resistance of steel due to surface alloying during mechanical pulse treatment comparing with the same treatment without surface alloying is shown. This is explained by the formation of the nanostructure with less grain size and higher microhardness, as well as the effect of alloying elements on the structure formation with lower electrochemical potentials, which are more favourable for secondary structures formation due to surface activation during wear resistance tests.
References
- V. M. Posuvailo, I. V. Kovalchuk, and I. B. Ivasenko, “Influence of hydrogen peroxide on the composition and porosity of oxide-ceramic coatings on alloys of the Al-Si-Cu and Al-Cu-Mg systems,” Mater. Sci., 57, No. 6, 894-899 (2022). https://doi.org/10.1007/s11003-022-00619-5
- Y. Li, D. Raabe, M. Herbig, P.-P. Choi, S. Goto, A. Kostka, Y. Hiroshi, C. Borchers, and R. Kirchheim, “Segregation stabilizes nanocrystalline bulk steel with near theoretical strengthk,” Physical Review Letters, 113, Is. 10 (2014). Article number 106104. https://doi.org/10.1103/PhysRevLett.113.106104
- L. Quintino, “Overview of coating technologies,” in: Surface Modification by Solid State Processing,Woodhead Publishing, Sawston (2014), pp. 1-24. https://doi.org/10.1533/9780857094698.1
- A. I. Balitskii, M. R. Havrilyuk, V. O. Balitska, V. O. Kolesnikov, and L. M. Ivaskevych, “Increasing turbine hall safety by using fire-resistant, hydrogen-containing lubricant cooling liquid for rotor steel mechanical treatment,” Energies, 16, Is. 1 (2023). Article number 535. https://doi.org/10.3390/en16010535
- V. M. Hvozdetskyi, M. M. Student, I. M. Pokhrelyuk, O. Z. Student, K. R. Zadorozhna, A. G. Lukyanenko, “Mechanical properties and corrosion resistance of arc coating sprayed by cored wires,” Mater. Sci., 60, No. 1, 79-84 (2024). https://doi.org/10.1007/s11003-024-00855-x
- M. Student, I. Pohrelyuk, J. Padgurskas, R. Raimundas, V. Hvozdetskhyi, K. Zadorozhna, H. Veselivska, O. Student, and O. Tkachuk, “Abrasive wear resistance and tribological characteristics of pulsed hard anodized layers on aluminum alloy 1011 in tribocontact with steel and ceramics in various lubricants,” Coatings, 13, Is. 11 (2023). Article number 1883. https://doi.org/10.3390/coatings13111883
- V. M. Posuvailo, M. D. Klapkiv, M. M. Student, Y. Y. Sirak, and H. V. Pokhmurska, “Gibbs energy calculation of electrolytic plasma channel with inclusions of copper and copper oxide with Al-base,” IOP Conf. Series: Materials Science and Engineering, 181, Is. 1 (2017). Article number 012045. https://doi.org/10.1088/1757-899X/181/1/012045
- M. M. Student, S. I. Markovych, V. M. Hvozdetsyi, O. S. Kalakhan, and V. M. Yuskiv, “Abrasive wear resistance and tribological characteristics of electrometallized composite coatings,” Mater. Sci., 58, No. 1, 96-104 (2022). https://doi.org/10.1007/s11003-022-00636-4
- M. Bembenek, V. Kopei, L. Y. Ropyak, and K. Levchuk, “Stressed state of chrome parts during diamond burnishing,” Metallofizika i Noveishie Tekhnologii [in Ukrainian], 45, Is. 2, 239-250 (2023). https://doi.org/10.15407/mfint.45.02.0239
- I. P. Shatskyi, L. Y. Ropyak, and M. V. Makoviichuk, “Strength optimization of a two-layer coating for the particular local loading conditions,” Strength of Materials, 48, Is. 5, 726-730 (2026). https://doi.org/10.1007/s11223-016-9817-5
- R. M. Miranda, J. P. Gandra, P. Vilaca, L. Quintino, and T. G. Santos, Surface Modification by Solid State Processing, Cambridge, Woodhead Publishing (2013).
- V. V. Prokopiv, O. B. Kostyuk, B. S. Dzyndra, T. M. Mazur, L. V. Turovska, O. M. Matkivskyi, and M. V. Deychakivskyi, “Electrical properties of CdTe thin layers obtained by Ca chemical doping,” Physics and Chemistry of Solid State, 20, Is. 4, 372-375 (2019). https://doi.org/10.15330/pcss.20.4.372-375
- V. Kyryliv, Y. Kyryliv, and N. Sas, “Formation of surface ultrafine grain structure and their physical and mechanical characteristics using vibration-centrifugal hardening,” Adv. in Mater. Sci. and Eng., (2018). Article number 3152170. https://doi.org/10.1155/2018/3152170
- A. V. Khomenko, “Severe plastic deformation: Methods and mathematical models of nanomaterials formation,” J. of Physical Studies, 24, Is. 2, 1-20 (2020). https://doi.org/10.30970/jps.24.2001
- V. Gurey, and I. Hurey, “The effect of the hardened nanocrystalline surface layer on durability of guideways,” in: Advanced Manufacturing Processes. (InterPartner 2019). Lecture Notes in Mechanical Engineering, Springer, Cham (2020), pp. 63-72. https://doi.org/10.1007/978-3-030-40724-7_7
- M. O. Vasylyev, B. N. Mordyuk, S. M. Voloshko, and D. A. Lesyk, “Microstructure evaluation of the carbon steels during surface severe plastic deformation,” Progress in Physics of Metals, 22, Is. 4, 562-618 (2021). https://doi.org/10.15407/ufm.22.04.562
- V. Gurey, P. Maruschak, I. Hurey, V. Dzyura, T. Hurey, and W. Wojtowicz, “Dynamic analysis of the thermo-deformation treatment process of flat surfaces of machine parts,” J. of Manufact. and Mater. Proces., 7, Is. 4 (2023). Article number 101. https://doi.org/10.3390/jmmp7030101
- W. Lei, Y. Yong, W. Yaming, and J. Ying, “Effect of nanocrystalline surface and iron-containing layer obtained by SMAT on tribological properties of 2024 Al alloy,” Rare Metal Mater. and Eng., 44, Is. 6, 1320-1325 (2015). https://doi.org/10.1016/S1875-5372(15)30082-5
- T. N. Kalichak, V. I. Kyryliv, and S. V. Fenchyn, “Mechanopulsed hardening of long components of the hydraulic cylinder rod type,” Mater. Sci., 25, No. 1, 96-99 (1989). https://doi.org/10.1007/BF00727938
- H. M. Nykyforchyn, V. I. Kyryliv, D. V. Slobodjan, and J. M. Koval, “Structural steels surface modification by mechanical pulse treatment for corrosion protection and wear resistance,” Surf. and Coat. Technol., 100-101, Is. 1-3, 125-127 (1998). https://doi.org/10.1016/S0257-8972(97)00600-2
- V. I. Kyryliv, B. P. Chaikovs’kyi, O. V. Maksymiv, and A. V. Shal’ko, “Contact fatigue of 20KhN3A and 55SMFA steels with surface nanostructured layers in corrosive-abrasive media,” Mater. Sci., 53, No. 4, 508-513 (2018). https://doi.org/10.1007/s11003-018-0103-5
- V. I. Kyryliv, and Y. M. Koval, “Surface alloying of steels from special process media,” Mater. Sci., 37, No. 5, 816-819 (2001). https://doi.org/10.1023/A:1015060829045
- B. I. Kostetskyi, I. G. Nosovskyi, A. K. Karaulov, L. I. Bershadskyi, N. B. Kostetskaya, V. A. Lyashkov, and M. F. Sagach, Surface Strength of Materials under Friction, Tekhnika, Kyiv (1976).
- W. Krous, and G. Nolze, “Powder cell – a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns,” J. Appl. Cryst., 29, 301-303 (1996). https://doi.org/10.1107/S0021889895014920
- Powder Diffraction File Search Manual: Alphabetical Listing and Search Section of Frequently Encountered Phases, JCPDS, Philadelphia (1974).
- E. E. Glikman, and R. E. Bruver, “Equilibrium segregation at the grain boundaries and intercrystalline cold brittleness of solid solutions,” Metallofizika [in Russian], 43, 42-43 (1972).
- I. V. Kragelskyi. M. N. Dobychyn, and V. S. Kombalov, Fundamentals of Friction and Wear Calculations [in Russian], Mashinostroyeniye, Moscow (1977).
- P. Guo, S. Ma, M. Jiao, P. Lv, J. Xing, L. Xu, and Z. Huang, “Effect of chromium on microstructure and oxidation wear behavior of high-boron high-speed steel at elevated temperatures,” Materials, 15, Is. 2 (2022). Article number 557. https://doi.org/10.3390/ma15020557