ISSN 0430-6252. Physicochemical Mechanics of Materials. 2023.
Volume 59, Issue 2
Anticorrosion properties of composite inhibiting pigment based on natural calcium silicate and zinc monophosphate
Keywords
an aluminum alloy corrosion, natural calcium silicate, zinc monophosphate, anticorrosion pigment, atmospheric precipitation, potentiodynamic polarization, impedance spectroscopy, scanning electron microscopy.
Cite as
Khlopyk O. P., Zin I. M., Datsko B. M., Bilyy L. M., Duriagina Z. A., and Korniy S. A. Anticorrosion properties of composite inhibiting pigment based on natural calcium silicate and zinc monophosphate. Physicochemical Mechanics of Materials. 2023. 59(2), 109-116.
https://doi.org/10.15407/pcmm2023.02.109
Abstract
A composite inhibiting pigment based on natural silicate – wollastonite and acid salt (zinc monophosphate) was obtained by the method of mechanochemical modification. The new composite pigment wollastonite–zinc monophosphate has high protective properties on aluminum alloy in the environment of weakly acidic atmospheric precipitation, and is superior to a simple mixture of calcium silicate and zinc monophosphate in protective characteristics. According to the research results, an effective corrosion-resistant film consisting of calcium, zinc and aluminum phosphates is formed on the surface of the alloy in the extraction of the composite pigment.
References
- S. B. Lyon, R. Bingham, and D. J. Mills, “Advances in corrosion protection by organic coatings: What we know and what we would like to know,” Prog. in Org. Coat., 102, 2-7 (2017). https://doi.org/10.1016/j.porgcoat.2016.04.030
- O. Gharbi, S. Thomas, C. Smith, and N. Birbilis, “Chromate replacement: what does the future hold?,” npj Materials Degradation, 2, Is. 1, art. no. 12 (2018). https://doi.org/10.1038/s41529-018-0034-5
- D. M. Lenz, M. Delamar, and C. A. Ferreira, “Improvement of the anticorrosion properties of polypyrrole by zinc phosphate pigment incorporation,” Prog. in Org. Coat., 58, Is. 1, 64-69 (2007). https://doi.org/10.1016/j.porgcoat.2006.12.002
- S. M. Mousavifard, P. M. Mohammadi Nouri, M. M. Attar, and B. Ramezanzadeh, “The effects of zinc aluminum phosphate (ZPA) and zinc aluminum polyphosphate (ZAPP) mixtures on corrosion inhibition performance of epoxy/polyamide coating,” J. of Industrial and Eng. Chemistry, 19, Is. 3, 1031-1039 (2013). https://doi.org/10.1016/j.jiec.2012.11.027
- R. Naderi, and M. M. Attar, “The role of zinc aluminum phosphate anticorrosive pigment in Protective Performance and cathodic disbondment of epoxy coating,” Corros. Sci., 52, Is. 4, 1291-1296 (2010). https://doi.org/10.1016/j.corsci.2009.12.019
- I. M. Zin’, S. B. Lyon, L. M. Bilyi, and M. B. Tymus’, “Specific features of the corrosion inhibition of an aluminum alloy by a nonchromate pigment mixture,” Mater. Sci., 44, No. 5, 638-645 (2008). https://doi.org/10.1007/s11003-009-9136-0
- V. I. Pokhmurs’kyi, I. M. Zin’, and S. B. Lyon, “Inhibition of corrosion by a mixture of nonchromate pigments in organic coatings on galvanized steel,” Mater. Sci., 40, No. 3, 383-390 (2004). https://doi.org/10.1007/s11003-005-0007-z
- C. H. Hare, “Mechanisms of corrosion protection with surface-treated wollastonite pigments,” Paint and Coatings Industry, 14, Is. 3, 74-82 (1998).
- C. H. Hare, Corrosion Control of Steel by Organic Coatings, in: Uhlig’s Corrosion Handbook: Third Edition(2011), pp. 971-983. https://doi.org/10.1002/9780470872864.ch67
- Z. A. Mansurov, N. N. Mofa, and T. V. Chernoglazova, Wollastonite – a Universal Reinforcing Filler of Composite Materials[in Russian], Al-Farabi Univer., Almaty (2018).
- J. Schott, O. S. Pokrovsky, O. Spalla, F. Devreux, A. Gloter, and J. A. Mielczarski, “Formation, growth and transformation of leached layers during silicate minerals dissolution: The example of wollastonite,” Geochimica et Cosmochimica Acta, 98, 259-281 (2012). https://doi.org/10.1016/j.gca.2012.09.030
- D. C. Southam, T. W. Lewis, A. J. Mc Farlane, T. Borrmann, and J. H. Johnston, “Calcium-phosphorus interactions at a nanostructured silicate surface,” J. of Colloid and Interface Sci., 319, Is. 2, 489-497 (2008). https://doi.org/10.1016/j.jcis.2007.12.012
- S. Korniy, I. Zin, S. Halaichak, B. Datsko, O. Khlopyk, M.-O. Danyliak, and M. Holovchuk, “Physico-chemical properties of anti-corrosion pigment based on nanoporous zeolite and zinc monophosphate,” App. Nanoscience (Switzerland), 13, Is. 7, 4685-4692 (2022). https://doi.org/10.1007/s13204-022-02592-6
- S. A. Korniy, I. M. Zin, M.-O. M. Danyliak, O. P. Khlopyk, V. S. Protsenko, L. M. Bilyi, M. Ya. Holovchuk, and Ya. I. Zin, “Protective properties of mechanochemically fabricated zeolite/phosphate anticorrosion pigments for paint coatings,” Voprosy Khimii i Khimicheskoi Tekhnologii, No. 3, 107-112 (2021). https://doi.org/10.32434/0321-4095-2021-136-3-107-112
- D. Battocchi, A. M. Simões, D. E. Tallman, and G. P. Bierwagen, “Comparison of testing solutions on the protection of Al-alloys using a Mg-rich primer,” Corros. Sci., 48, Is. 8, 2226-2240 (2006). https://doi.org/10.1016/j.corsci.2005.05.059
- I. M. Voloshyn, and O. R. Sobechko, Acid Precipitation of the City of Lviv: their Chemistry, Metallization of Natural Components[in Ukrainian], Lviv State Univ. of Physical Culture, Lviv (2013).
- http://www.abc.chemistry.bsu.by/vi/analyser/
- P. Ptáček, M. Nosková, J. Brandštetr, F. Šoukal, and T. Opravil, “Dissolving behavior and calcium release from fibrous wollastonite in acetic acid solution,” Thermochimica Acta, 498, Iss. 1-2, 54-60 (2010). https://doi.org/10.1016/j.tca.2009.10.002
- P. Laniesse, C.C. Dit Coumes, A. Poulesquen, A. Bourchy, A. Mesbah, G. Le Saout, and P. Gaveau, “Setting and hardening process of a wollastonite-based brushite cement,” Cement and Concrete Res., 106, 65-76 (2018). https://doi.org/10.1016/j.cemconres.2018.01.019
- F. Mansfeld, S. Lin, S. Kim, and H. Shih, “Pitting and passivation of Al alloys and Al-based metal matrix composites,” J. of the Electrochem. Soc., 137, Is. 1, 78-82 (1990). https://doi.org/10.1149/1.2086442
- Y. J. Tan, S. Bailey, and B. Kinsella, “An investigation of the formation and destruction of corrosion inhibitor films using electrochemical impedance spectroscopy (EIS),” Corros. Sci., 38, Is. 9, 1545-1561 (1996). https://doi.org/10.1016/0010-938X(96)00047-9
- E. A. A. Mohammed, M. De Keersmaecker, and A. Adriaens, “Inhibition of the corrosion of iron heritage objects after treatment with long-chain monocarboxylic acids in ethanolic solutions,” Prog. in Org. Coat., 101, 225-232 (2016). https://doi.org/10.1016/j.porgcoat.2016.07.011