ISSN 0430-6252. Physicochemical Mechanics of Materials. 2023.
Volume 59, Issue 2

Inhibition of carbon steel corrosion by polyvinylpyrrolidone in chloride-acetate solution and in model strattal water

Keywords

environment friendly inhibitors, polyvinylpyrrolidone, corrosion rate, degree of protection, gravimetric and polarization studies.

Cite as

Slobodyan Z. V., Mahlatiuk L. A., Kupovych R. B., and Sobodosh N. Yo. Inhibition of carbon steel corrosion by polyvinylpyrrolidone in chloride-acetate solution and in model strattal water. Physicochemical Mechanics of Materials. 2023. 59(2), 117-122.

https://doi.org/10.15407/pcmm2023.02.117

Abstract

The influence of polyvinylpyrrolidone (PVP) with molecular mass of 12600 and 28000 at concentrations of 0.2; 0.5 and 1 g/dm3 on the corrosion rate of 20 steel in the chloride-ace­tate solution and in the model reservoir water was investigated by gravimetric and electro­chemical methods. Under dynamic conditions maximum inhibition of the steel corrosion rate is observed at a PVP concentration of 0.5 g/dm3 in both media. A further increase in inhibitor concentration to 1 g/dm3 reduces the degree of protection more significantly in chloride-acetate solution than in the reservoir water. The PVP with a higher molecular mass exhibits higher protective properties, which is typical of polymers capable of adsor­bing both linearly and in a ball.

References

  1. P. P. Vyrvynskyi, and V. L. Khomenko, Repair of Wells[in Ukrainian], National Mining University, Dnipropetrovsk (2003).
  2. V. S. Boiko, R. M. Kondrat, and R. S. Yaremijchyk (Eds.), Handbook on Oil and Gas Business[in Ukrainian], Kyiv-Lviv (1996).
  3. R. M. Kondrat, and O. R. Kondrat, “Analysis of the causes of salt deposits and methods of their control during the operation of gas and gas condensate wells,” Prospecting and Development of Oil and Gas Fields[in Ukrainian], 2, 27-31 (2008).
  4. M. Akrout, I. Bousselmi, E. Trinki, S. Maximovich, and F. Dalard, “Effect non-toxic corrosion inhibitors on steel in chloride solution,” J. of Mat. Sci., 39, Is. 24, 7341-7350 (2004). https://doi.org/10.1023/B:JMSC.0000048749.31437.b9
  5. A. Singh, K. R. Ansari, and M. A. Quraishi, “Inhibition effect of natural polysaccharide composite on hydrogen evolution and P110 steel corrosion in 3.5 wt% NaCl solution saturated with CO2: Combination of experimental and surface analysis,” Int. J. of Hydrogen Energy, 45, Is. 46, 25398-25408 (2020). https://doi.org/10.1016/j.ijhydene.2020.06.288
  6. S. A. Korniy, I. M. Zin, M. B. Tymus, O. P. Khlopyk, and M. Y. Holovchuk, “Steel corrosion inhibition by microbial polysaccharide and tartrate mixture,” J. of Bio- and Tribo-Corrosion, 8, Is. 1, art. no. 6 (2022). https://doi.org/10.1007/s40735-021-00605-5
  7. G. Palumbo, K. Kollbec, R. Wirecka, A. Bernasik, and M. Gorny, “Effect of CO2partial pressure on the corrosion inhibition of N80 carbon steel by gum arabic in a CO2-water saline environment for shale oil and gas industry,” Materials, 13, Is. 19, art. no. 4245 (2020). https://doi.org/10.3390/ma13194245
  8. M.-O. Danyliak, and Yu. Ya. Rizun, “Gum arabic as an environmentally friendly inhibitor for corrosion protection of 09G2S steel in neutral media,” Mater. Sci., 58, No. 1, 47-53 (2022). https://doi.org/10.1007/s11003-022-00629-3
  9. S. A. Umoren, A. A. AlAhmary, Z. M. Gasem, and M. M. Solomon, “Evaluation of chitosan and carboxymethyl cellulose as ecofriendly corrosion inhibitors for steel,” Int. J. Boil Macromol., 117, 1017-1028 (2018). https://doi.org/10.1016/j.ijbiomac.2018.06.014
  10. Ye. P. Kovalchyk, O. V. Resetnyak, Selfogranized Layers on Solid Surface[in Ukrainian], Ivan Franko State Univ. Publ. House, Lviv (2006).
  11. F. Haaf, A. Sanner, and F. Straub, “Polymers of n-vinylpyrrolidone: Synthesis, characterization and uses,” Polymer Journal, 17, Is. 1, 143-152 (1985). https://doi.org/10.1295/polymj.17.143
  12. H. Gerengi, H. I. Ugras, M. M. Solomon, S. A. Umoren, M. Kurtay, and N. Atar, “Synergistic corrosion inhibition effect of 1-ethyl-1-methylpyrrolidinium tetrafluoroborate and iodide ions for low carbon steel in HCl solution,” J. of Adhesion Sci. and Techn., 30, Is. 21, 2383-2403 (2016). https://doi.org/10.1080/01694243.2016.1183407
  13. N. M. Velikonskaya, and A. A. Nadtochiy, Surface Phenomena and Dispersed Systems [in Ukrainian], State Metallurgical Academy of Ukraine, Dnipro (2018).