ISSN 0430-6252. Physicochemical Mechanics of Materials. 2024.
Volume 60, Issue 1

Comparative analysis of the kinetics of martensitic transformation in low-alloy structural steel by dilatometric and calculation methods

Keywords

martensite, austenite, transformation, phase, modeling.

Cite as

Chuiko I. M., Parusov E. V., Bobyr S. V., Sahura L. V., and Parusov O. V. Comparative analysis of the kinetics of martensitic transformation in low-alloy structural steel by dilatometric and calculation methods. Physicochemical Mechanics of Materials. 2024. 60(1), 063-069.

https://doi.org/10.15407/pcmm2024.01.063

Abstract

A comparative analysis of the athermal martensitic transformation kinetics in low-alloy 30CrMnSi structural steel using dilatometric and calculative methods was carried out. At the initial stage the evolution curve of shear transformation according to the Koistinen–Marburger (KM) model corresponds well to the experimental dilatometric data, but with further temperature decrease the mathematical modeling causes a signifi­cant error in determining the volume fraction of the formed martensite. At the same time, the error in the calculations of the martensitic phase amount can reach 20 vol.%. The proposed method, which takes into account the temperatures of the begin­ning and completion of the shear transformation of austenite, allowed obtaining a closer correlation with the dilatometric data of 30CrMnSi steel compared to the Koistinen–Marburger model. The obtained results can be used to improve the existing modes of heat treatment, including interrupted quenching, in order to increase the accuracy of predictive determina­tion of phase composition in low-alloyed structural steels.

References

  1. J. W. Christian, The Theory of Transformations in Metals and Alloys, Pergamon, Oxford (2002). https://doi.org/10.1016/B978-008044019-4/50022-2
  2. E. J. Mittemeijer, “Review analysis of the kinetics of phase transformation,” J. Mater. Sci., 27, 3977-3987 (1992). https://doi.org/10.1007/BF01105093
  3. S. Bobyr, E. Parusov, T. Golubenko, and I. Chuiko, “Diffusion model of austenite decomposition with considering its stabilization in alloyed steel,” Metallofizika i Noveishie Tekhnologii [in Russian], 44, Is. 1, 31-45 (2022). https://doi.org/10.15407/mfint.44.01.0031
  4. T. A. Kop, J. Sietsma, and S. Van Der Zwaag, “Dilatometric analysis of phase transformations in hypo-eutectoid steels,” J. Mater. Sci., 36, 519-526 (2001). https://doi.org/10.1023/A:1004805402404
  5. S. Salari, M. Naderi, U. Prahl, and W. Bleck, “Quantification of phase transformation kinetics under thermomechanical conditions using dilatometry data,” Adv. Mater. Res., 622-623, 581-584 (2012). https://doi.org/10.4028/www.scientific.net/AMR.622-623.581
  6. M. Morawiec, A. Skowronek, M. Król, and A. Grajcar, “Dilatometric analysis of the austenite decomposition in undeformed and deformed low-carbon structural steel,” Materials, 13, Is. 23 (2020). Article number 5443. https://doi.org/10.3390/ma13235443
  7. V. A. Kostin, V. D. Pozniakov, O. M. Berdnikova, V. V. Zhukov, T. O. Alekseyenko, and I. I. Alekseyenko, “The influence of structural transformations on mechanical properties of welded joints of armoured steels,” Mater. Sci., 56, No. 4, 472-480 (2001). https://doi.org/10.1007/s11003-021-00453-1
  8. S. Ghosh, P. Kaikkonen, V. Javaheri, A. Kaijalainen, I. Miettunen, M. Somani, J. Komi, and S. Pallaspuro, Design of tough, ductile direct quenched and partitioned advanced high-strength steel with tailored silicon content,” J. of Mater. Res. and Technol., 17, 1390-1407 (2022). https://doi.org/10.1016/j.jmrt.2022.01.073
  9. D. P. Koistinen, and R. E. Marburger, “A general equation prescribing the extent of the austenitemartensite transformation in pure iron-carbon alloys and plain carbon steels,” Acta Metallurgica, 7, 59-60 (1959). https://doi.org/10.1016/0001-6160(59)90170-1
  10. S. V. Bobyr, E. V. Parusov, G. V. Levchenko, A. Yu. Borisenko, and I. M. Chuiko, “Shear transformation of austenite in steels considering stresses’ effects,” Progress in Physics of Metals, 23, Is. 3, 379-410 (2022). https://doi.org/10.15407/ufm.23.03.379
  11. ASTM International (A1033-18), Standard Practice for Quantitative Measurement and Reporting of Hypoeutectoid Carbon and Low-alloy Steel Phase Transformations. (2018).
  12. H.-S. Yang, and H. K. D. H. Bhadeshia, “Uncertainties in dilatometric determination of martensite start temperature,” Mat. Sci. Tech., 23, Is. 5, 556-560 (2007). https://doi.org/10.1179/174328407X176857
  13. L. Liu, and B. Guo, “Dilatometric analysis and kinetics research of martensitic transformation under a temperature gradient and stress,” Materials, 14, 7271 (2021). https://doi.org/10.3390/ma14237271
  14. M. Gomez, S. F. Medina, and G. Caruana, Modelling of phase transformation kinetics by correction of dilatometry results for a ferritic Nb-microalloyed steel,” ISIJ Int., 43, 1228-1237 (2003). https://doi.org/10.2355/isijinternational.43.1228
  15. O. P. Ostash, V. V. Kulyk, V. D. Pozniakov, O. A. Haivoronskyi, and V. V. Vira, “Influence of the modes of heat treatment on the strength and cyclic crack-growth resistance of 65G steel,” Mater. Sci., 54, No. 6, 776-782 (2019). https://doi.org/10.1007/s11003-019-00263-6
  16. E. V. Parusov, S. V. Bobyr, I. Yu. Prykhodko, I. M. Chuiko, and S. S. Zakharchuk, “Prediction of the structural state of the working layer of large-size rolls during thermal hardening,” Metal Sci. and Heat Treat. of Met., Is. 1(100), 39-45 (2023). https://doi.org/10.30838/J.PMHTM.2413.280323.39.943