ISSN 3041-1815. Physicochemical Mechanics of Materials. 2024.
Volume 60, Issue 3

Complex modification of heat-resistant ZhS3DK-VІ alloy with yttrium and titanium carbonitride

Keywords

heat-resistant nickel alloy, cast sample, chemical composition, modification, yttrium, titanium carbonitride, hot isostatic pressing, macro- and microstructure, mechanical properties, impact toughness, long-term strength.

Cite as

Danilov S. M., Tomkin D. O., Pedash O. O., Naumyk O. O., and Naumyk V. V. Complex modification of heat-resistant ZhS3DK-VІ alloy with yttrium and titanium carbonitride. Physicochemical Mechanics of Materials. 2024. 60(3), 137-143.

https://doi.org/10.15407/pcmm2024.03.137

Abstract

Samples cast from heat-resistant nickel ZhS3DK-VІ alloy, complex modified with yttrium and titanium carbonitride in various combinations, after hot isostatic pressing (HIP) and subsequent heat treatment, were investigated. For comparison, complex modifi­cation was performed with the simultaneous use of yttrium and cerium. It was established that the chemical composition (taking into account the presence of yttrium in the alloys), as well as the mechanical and heat-resistant properties of the cast samples meet the requi­rements of OST 1.90.126-85, with the exception of the impact ductility of the samples without titanium carbonitride, which is almost twice lower than the additional require­ments put forward by the developer for responsible aircraft castings, and also for the sam­ples with titanium carbonitride. The best modifying effect was obtained with the complex modified alloy with 0.075% titanium carbonitride. In other options, there is a coarse­ning of the structure, and for the samples without titanium carbonitride, melting of the eutectic (γ-γ)′-phase is also observed, which probably contributs to the reduction of im­pact toughness. As a result of HIP, micropores and loosening which do not reach the surface of the parts (located in the internal volumes of the metal) are healed, which contributes to the stabili­zation of the  material structure and properties.

References

  1. G. H. Badeer, GE Aeroderivative Gas Turbines. Design and Operating Features, Evendale, GE Power Systems (2000).
  2. O. G. Fedorov, Gas Turbines and Gas-Turbine Installations [in Ukrainian], Odessa Technologichnyi Yniversytet, Odesa (2013).
  3. A. A. Khalatov, K. A. Yushchtnko, B. V. Isakov, Yu. Ya. Dashevskyi, and A. P. Shevtsov, “Gas turbine construction in Ukraine: current state and development prospects,” [in Ukrainian] Visnyk Natsionalnoi Academii Nauk Ukrainy, Is. 12, 40-49 (2013).
  4. R. C. Reed, The Superalloys Fundamentals and Applications, Cambridge University Press, Cambridge (2006). https://doi.org/10.1017/CBO9780511541285
  5. M. Perrut, P. Caron, M. Thomas, and A. Couret, “High temperature materials for aerospace applications: Ni-based superalloys and g-TiAl alloys,” Comptes Rendus, Physique, 8, Is. 19, 657-671 (2018). https://doi.org/10.1016/j.crhy.2018.10.002
  6. D. V. V. Satyanarayana, and N. E. Prasad, “Nickel-based superalloy,” in: Aerospace Materials and Material Technologies. Vol. 1: Aerospace Materials, Springer Nature, Pte Ltd., Singapore (2017), pp. 199-228. https://doi.org/10.1007/978-981-10-2134-3_9
  7. V. Ye. Khrychykov, and O. V. Menyailo, Foundry Production of Ferrous and Non-Ferrous Metals [in Ukrainian], Natsionalna Metalurgijna Academiya Ukrainy, Dnipropetrovsk, (2013).
  8. Yu. I. Kvasnytska, Increasing the Operational Characteristics of Heat-Resistant Corrosion-Resistant Nickel-Based Alloys and the Development of Obtaining Gas-Turbine Blades Technology [in Ukrainian], Abstract of Dortoral Degree Thesis (Engineering), Kyiv (2018).
  9. V. L. Greshta, “Structural liability of sheet-rolled corrosion-resistant ferritic steels to a plastic deforming,” Metallofizika i Noveishie Tekhnologii, 39, Is. 9, 1213-1225 (2017). https://doi.org/10.15407/mfint.39.09.1213
  10. V. O. Bohuslayev, S. I. Repiakh, V. G. Mohylatenko, Z. A. Ivchenko, and M. O. Metveeva, Foundry Properties of Metals and Alloys for Precision Casting [in Ukrainian], “Motor-Sich”, Zaporizhzhya (2016).
  11. A. Rowe, J. Wells, G. D. West, and R. C. Thomson, “Microstructural evolution of single crystal and directionally solidified rejuvenated nickel superalloys,” Proc. 12th Int. Symp. on Superalloys (2012), pp. 245-254. https://doi.org/10.1002/9781118516430.ch27
  12. É. I. Tsivirko, P. D. Zhemanyuk, V. V. Klochikhin, V. V. Naumik, and V. V. Lunev, “Crystallization processes, structure and properties of Ni superalloy castings,” Metallovedenie i Termicheskaya Obrabotka Metallov, Is. 10, 13-17 (2001). https://doi.org/10.1023/A:1013648719105
  13. V. P. Kuznetsov, V. P. Lesnikov, I. P. Konakova, N. A. Popov, and Yu. G. Kvasnitskaya, “Structural and phase transformations in single-crystal rhenium- and ruthenium-alloyed nickel alloy under testing for long-term strength,” Metal Sci. and Heat Treatment, 57, Is. 7-8, 503-506 (2015). https://doi.org/10.1007/s11041-015-9912-4
  14. Z. H. Dong, D. Sergeev, D. Kobertz, N. D’Souza, S. Feng, M. Müller, and H. B. Dong, “Vaporization of Ni, Al and Cr in Ni-base alloys and its influence on surface defect formation during manufacturing of single-crystal components,” Metallurgical and Mat. Transact. A, 51, Is. 1, 309-322 (2020). https://doi.org/10.1007/s11661-019-05498-1
  15. J. B. Wahl, and K. Harris, “CMSX-4® plus single-crystal alloy development, characterization and application development,” in: Superalloys, John Wiley & Sons, Inc., Hoboken, New Jersey (2016), pp. 25-33. https://doi.org/10.1002/9781119075646.ch3
  16. K. Kawagishi, A.-C. Yeh, T. Yokokawa, and T. Kobayashi, “Development of an oxidation-resistant high-strength sixth-generation single-crystal superalloy TMS-238,” in: Superalloys, John Wiley & Sons, Inc., Hoboken, New Jersey (2012), pp. 189-195. https://doi.org/10.1002/9781118516430.ch21
  17. G. L. Erickson, “The development of the CMSX-11B and CMSX-11C alloys for industrial gas turbine application,” in: Superalloys, John Wiley & Sons, Inc., Hoboken, New Jersey (1996), pp. P. 45-62. https://doi.org/10.7449/1996/Superalloys_1996_45_52
  18. J. B. Wahl, and K. Harris,”New single-crystal superalloys, CMSX®-7 and CMSX®-8,” in: Superalloys, John Wiley & Sons, Inc., Hoboken, New Jersey (2012), pp. 179-188. https://doi.org/10.7449/2012/Superalloys_2012_179_188
  19. E. Milonin, and V. Naumyk, “Rhenium-free heat-resistant nickel alloy for the cast blades production,” TMS 2024 153rd Annual Meeting & Exhibition Supplemental Proceedings, The Minerals, Metals & Materials Series, Springer, Cham (2024), pp. 1707-1712. https://doi.org/10.1007/978-3-031-50349-8_146
  20. A. M. Verkhovlyuk, A. V. Narivskyi, and V. G. Mohylatenko, Technologies for Obtaining Metals and Alloys for Foundry Production [in Ukrainian], “Vinnichenko” Publ. House, Kyiv (2016).
  21. V Klochikhin, and V. Naumyk, “Improvement of technological processes obtaining a heatresistant nickel alloys for turbine blades using foundry return,” Mat. Sci. and Techn., 34, 1454-1458 (2019). https://doi.org/10.7449/2019/MST_2019_1454_1458
  22. Y. L. Sanchugov, A. D. Koval, and S. B. Belikov, “Some peculiarities of alloying of nickel superalloys resistant to high-temperature corrosion,” Proc. NACE, Int. Corr. Conf., Ser. 4 (2012), pp. 3435-3438. https://doi.org/10.5006/C2012-01429
  23. O. E. Narivskyi, S. B. Belikov, S. A. Subbotin, and T. V. Pulina, “Influence of chloride-containing media on the pitting resistance of AISI 321 steel,” Mater. Sci., 57, No. 4, 291-297 (2021). https://doi.org/10.1007/s11003-021-00544-z
  24. V. O. Bohuslayev, K. B. Balushok, V. V. Klochikhin, Ye. V. Milonin, V. V. Naumyk, and V. A. Shalomeyev, Resource-Saving Technologies of Foundry Production for Aircraft Engine Construction [in Ukrainian], “Motor-Sich”, Zaporizhzhya (2021).
  25. Yunsong Zhao, Siliang He, and Longfei Li, “Application of hot isostatic pressing in nickel-based single crystal superalloy,” Crystals, 6, Is. 12, 805 (2022). https://doi.org/10.3390/cryst12060805
  26. I. M. Razumovskii, A. A. Tikhonov, S. F. Marinin, and A. V. Logunov, “Hot isostatic pressing improves the quality of the blades from nickel base superalloys for turbine engines,” Adv. Mat. Res., 278, 295-300 (2011). https://doi.org/10.4028/www.scientific.net/AMR.278.295
  27. Jun Wang and Zhaojun Jiang, “Application research progress of hot isostatic pressing tech-nology in nickel-based singlecrystal superalloy,” E3S Web of Conf. The 2nd Int. Symp. on Hydrogen Energy and Energy Technologies (HEET 2019), 155 (2020). Article Number 01012. https://doi.org/10.1051/e3sconf/202015501012
  28. V. Klochihin, N. Lysenko, and V. Naumyk, “Structure and properties of heat-resistant nickel alloys castings after hot isostatic pressing,” Mat. Sci. and Techn. Conf. and Exhibition, 2, 1370-1374 (2017). https://doi.org/10.7449/2017/mst_2017_1370_1374
  29. V. V. Klochykhin, O. O. Pedash, S. M. Danilov, D. O. Tyomkin, O. O. Naumyk, and V. V. Naumyk, “Hot isostatic pressing in the manufacture of ZhS3DK-VI alloy turbine blades with 50% returns in the charge,” Strength of Mater., 54, Is. 6, 1043-1049 (2022). https://doi.org/10.1007/s11223-023-00479-7
  30. D. O. Tomkin, O. O. Pedash, S. M. Danilov, V. V. Klochikhin, O. O. Naumyk, and V. V. Naumyk, “Structure and properties of cast blades made of ZhS3DK-VI alloy modified with nickel-yttrium ligature,” Mater. Sci., 59, No. 4, 480-486 (2024). https://doi.org/10.1007/s11003-024-00801-x