ISSN 0430-6252. Physicochemical Mechanics of Materials. 2024.
Volume 60, Issue 2

Properties of equiatomic high-entropy Laves phases of C14 type

Keywords

high-entropy alloys, Laves phase of type C14, mixing enthalpy, hardness, elastic modulus, distortion.

Cite as

Gorban’ V. F., Krapivka N. A., and Myslyvchenko O. М. Properties of equiatomic high-entropy Laves phases of C14 type. Physicochemical Mechanics of Materials. 2024. 60(2), 108-113.

https://doi.org/10.15407/pcmm2024.02.108

 

Abstract

Based on the results of studies of a number of high-entropy alloys (HEA), the conditions for the formation of Laves phases of type C14 were established. The influence of the electronic concentration of chemical elements on its content, as well as the hardness and modulus of elasticity of hard-soluble HEA with BCC and FCC lattices was estimated. Іt is found that a decrease in the parameters of the crystal lattice of the obtained phase leads to an increase in hardness and elastic modulus of alloys.

References

  1. S. Ranganathan, “Alloyed pleasures: multimetallic cocktails,” Current Sci., 85, 1404-1406 (2003).
  2. B. Cantor, I. Chang, P. Knight, and A. Vincent, “Microstructural development in equiatomic multicomponent alloys,” Mater. Sci. and Eng., A 375, 213-218 (2004). https://doi.org/10.1016/j.msea.2003.10.257
  3. J. W. Yeh, S. K. Chen, S. J. Lin, J. Y. Gan, T. S. Chin, and T. T. Shun, “Nanostructured high entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes,” Adv. Eng. Mater., 6, 299-303 (2004). https://doi.org/10.1002/adem.200300567
  4. Sheng Guo, Chun Ng, Jian Lu, and C. T. Liu, “Effect of valence electron concentration on stability of FCC or BCC phase in high entropy alloys,” J. of Appl. Phys., 109, Is. 10 (2011). Article number 103505. https://doi.org/10.1063/1.3587228
  5. X. Yang, and Y. Zhang, “Prediction of high-entropy stabilized solid-solution in multi-component alloys,” Mater. Chem. Phys., 132, 233-238 (2012). https://doi.org/10.1016/j.matchemphys.2011.11.021
  6. S. A. Firstov, V. F. Gorban, N. A. Krapivka, M. V. Karpets, and É. P. Pechkovskii, “Structural materials research: Effect of electron density on phase composition of high-entropy equiatomic alloys,” Powder Metallurgy and Metal Ceramics, 54, 607-61 (2016). https://doi.org/10.1007/s11106-016-9754-7
  7. O. N. Senkov, G. B. Wilks, D. B. Miracle, C. P. Chuang, and P. K. Liaw, “Refractory high-entropy alloys,” Intermetallics, 18, Is. 9, 1758-1765 (2010). https://doi.org/10.1016/j.intermet.2010.05.014
  8. V. F. Gorban, S. A. Firstov, and M. O. Krapivka, “The influence of different factors on physicomechanical properties of high entropy alloys with fcc lattice,” Mater. Sci., 59, No. 2, 145-151 (2023). https://doi.org/10.1007/s11003-024-00755-0
  9. V. F. Gorban, S. O. Firstov, M. O. Krapivka, A. V. Samelyuk, and D. V. Kurylenko, “Influence of various factors on the properties of solid-soluble high-entropy alloys based on BCC and FCC phases,” Mater. Sci., 58, No. 1, 135-140 (2022). https://doi.org/10.1007/s11003-022-00641-7
  10. F. Otto, Y. Yang, H. Bei, and E. P. George, “Relative effects of enthalpy and entropy on the phase stability of equiatomic high entropy alloys,” Acta Mater., 61, 2628-2638 (2013). https://doi.org/10.1016/j.actamat.2013.01.042
  11. D. B. Miracle, and O.N. Senko, “A critical review of high entropy alloys and related concepts,” Acta Mater., 122, 448-511(2017). https://doi.org/10.1016/j.actamat.2016.08.081
  12. Z. Wang, Q. Fang, J. Li, B. Liu, and Y. Liu, “Effect of lattice distortion on solid solution strengthening of BCC high-entropy alloys,” Mater. Sci. Technol., 34, 349-354 (2018). https://doi.org/10.1016/j.jmst.2017.07.013
  13. C. Lee, G. Song, M. C. Gao, R. Feng, P. Chen, J. Brechtl, Y. Chen, K. An, W. Guo, J. D. Poplawsky, S. Li, A.T. Samaei, W. Chen, A. Hu, H. Choo, P. K. Liaw, “Lattice distortion in a strong and ductile refractory high-entropy alloy,” Acta Mater., 60, 158-172 (2018). https://doi.org/10.1016/j.actamat.2018.08.053
  14. Li Li, Qihong Fang, Jia Li, Bin Liu, Yong Liu, and Peter K. Liaw, “Lattice-distortion dependent yield strength in high entropy alloy,” Mater. Sci. and Eng., A., 784 (2020). Article number 139323. https://doi.org/10.1016/j.msea.2020.139323
  15. V. F. Gorban, N. A. Krapivka, S. A. Firstov, and D. V. Kurylenko, “The role of mixing enthalpy in the formation of physical and mechanical properties of solid-solvent high-entropy alloys,” Elektronna Mikroskopiya i Mitsnist Materialiv [in Ukrainian], Is. 25, 8-16 (2019).
  16. Tiandang Huang, Hui Jiang, Yiping Lu, Tongmin Wang, and Tingju Li, “Effect of Sc and Y addition on the microstructure and propertiesof HCP-structured high-entropy alloys,” Appl. Phys. A., 125 (2019). Article number 180. https://doi.org/10.1007/s00339-019-2484-1
  17. Akira Takeuchi, Takeshi Wada, and Hidemi Kato, “High-entropy alloys with hexagonal close-packed structure in Ir26Mo20Rh22.5Ru20W11.5 and Ir25.5Mo20Rh20Ru25W9.5 alloys designed by sandwich strategy for the valence electron con¬centration of constituent elements in the periodic chart,” Mat. Trans., 60, Is. 8, 1666-1673 (2019). https://doi.org/10.2320/matertrans.M2019037
  18. O. N. Senkov, J. M. Scott, S. V. Senkova, D. B. Miracle, and C. F. Woodward, “Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy,” J. Alloys Compounds, 509, Is. 20. 6043-6048 (2011). https://doi.org/10.1016/j.jallcom.2011.02.171
  19. O. N. Senkov, and C. F. Woodward, “Microstructure and properties of a refractory NbCrMo0.5Ta0.5TiZr alloy,” Mater. Sci. and Eng., A, 529, 311-320 (2011). https://doi.org/10.1016/j.msea.2011.09.033
  20. F. J. Wang, Y. Zhang, G. L. Chen, and H. A. Davies, “Cooling rate and size effect on the microstructure and mechanical properties of AlCoCrFeNi high entropy alloy,” J. Eng. Mater. Technol., 131 (2009). Article number 034501. https://doi.org/10.1115/1.3120387
  21. T. T. Shun, and Y. C. Du, “Microstructure and tensile behaviors of FCC Al0.3CoCrFeNi high entropy alloy,” J. of Alloys and Compounds, 479, 157-160 (2009). https://doi.org/10.1016/j.jallcom.2008.12.088
  22. H. S. Kim, and S. Praveen, “High-entropy alloys: potential candidates for high-temperature applications,” Adv. Eng. Mater., 20 (2017). https://doi.org/10.1002/adem.201700645
  23. X. Yang, and Y. Zhang, “Cryogenic resistivities of NbTiAlVTaLax, CoCrFeNiCu and CoCrFeNiAl high entropy alloys,” Adv. Mater. Process, 2010, 51-54 (2011). https://doi.org/10.1142/9789814322799_0012
  24. Jian Liang, Guanglong Li, Xin Ding, Yue Li, Zhen Wen, Tong Zhang, and Yingdong Qu, “Effect of C14 Laves/BCC on microstructure and hydrogen storage properties of (Ti32.5V27.5Zr7.5Nb32.5)1-xFex (x = 0.03, 0.06, 0.09) high entropy hydrogen storage alloys,” J. of Energy Storage, 73, 108852 (2003). https://doi.org/10.1016/j.est.2023.108852
  25. Yiping Lu, Yong Dong, Sheng Guo, Li Jiang, Huijun Kang, Tongmin Wang, Bin Wen, Zhijun Wang, Jinchuan Jie, Zhiqiang Cao, Haihui Ruan, and Tingju Li, “A promising new class of high-temperature alloys: eutectic high-entropy alloys,” Scientific Reports, 4 (2014). Article number 6200. https://doi.org/10.1038/srep06200
  26. X. Q. Gao, K. Zhao, H. B. Ke, D. W. Ding, W. H. Wang, and H. Y. Bai, “High mixing entropy bulk metallic glasses,” J. Non-Cryst. Solids, 357, 3557-3560 (2011). https://doi.org/10.1016/j.jnoncrysol.2011.07.016
  27. Xinliang Shi, Gong Li, Mengdi Zhang, Hanqing Xu, and Ziyang Li, “Laves phase assisted the passive behaviors of Co-free non-equiatomic CrFe-Ni-Nb eutectic high-entropy alloys,” J. of Alloys and Compounds, 960, 170905 (2003). https://doi.org/10.1016/j.jallcom.2023.170905
  28. B. X. Caoa, H. J. Kong, Z. Y. Ding, S. W. Wu, J. H. Luan, Z. B. Jiao, J. Lu, C. T. Liua, and T. Yanga, “A novel L12-strengthened multicomponent Co-rich high-entropy alloy with both high γ¢-solvus temperature and superior high-temperature strength,” Scripta Materialia, 199 (2021). Article number 113826. https://doi.org/10.1016/j.scriptamat.2021.113826
  29. S. A. Firstov, V. F. Gorban, and V. F. Pechkovskii, “New methodological possibilities for determining the mechanical properties of modern materials by the method of automatic indentation,” Nauka i Innovatsii [in Ukrainian], Is. 5, 7-18 (2010).
  30. A. R., Miedema, P. F de Chatel, and F. R. de Boer, “Cohesion in alloys – fundamentals of a semi-empirical model,” Physica B+C, 100, Is 1, 1-28 (1980). https://doi.org/10.1016/0378-4363(80)90054-6
  31. Electronic resource. Access mode: http://www.entall.imim.pl/calculator/
  32. Yasong Li, Wei-Bing Liao, Huaican Chen, Jamieson Brecht, Wenli Song, Wen Yin, Zhanbing He, Peter K. Liaw, and Yong Zhang, “A low-density high-entropy dual-phase alloy with hierarchical structure and exceptional specific yield strength,” Science China Materials, 66, Is.2, 780-792 (2003). https://doi.org/10.1007/s40843-022-2178-x
  33. V. F. Horban, M. O. Krapivka, S. O. Firstov, O. M. Myslyvchenko, I. M. Zakiev, and A. O. Samelyuk, “Refractory and ceramic materials mechanical and tribological properties of cast monocarbides and multicomponent high-entropy carbides,” Metal Ceramics, 62, 58-65 (2003). https://doi.org/10.1007/s11106-023-00369-2