ISSN 3041-1815. Physicochemical Mechanics of Materials. 2025.
Volume 61, Issue 2

Specific features of cementation of high-chromium martensitic-ferritic 06Kh18ch steel in a pasty carburizer

Keywords

chromium steels, cementation, ferrite, austenite, martensite, hardness, chromium carbides.

Cite as

Mishchenko V. G., Tonkonoh D. M., Bazhmina E. A., Kharchenko A. O., and Kornienko V. V. Specific features of cementation of high-chromium martensitic-ferritic 06Kh18ch steel in a pasty carburizer. Physicochemical Mechanics of Materials. 2025. 61(2), 046-051.

https://doi.org/10.15407/pcmm2025.02.046

Abstract

Martensitic-ferritic steels containing 20–30% martensite uniformly distributed in the plas­tic ferritic matrix were investigated. At a chromium concentration of more than 16% and a carbon content of about 0.06%, the steel undergoes a partial α→γ phase transformation. The presence of an austenite phase at temperatures above 875°C in such steels allows the application of diffusion saturation with carbon and, accordingly, increases the share of the martensitic component. The effect of cementation on the structure and mecha­nical properties of the surface of experimental 06Kh18сh steel and martensitic 95Kh18, 20Kh13 steels, was compared. The change in the structural composition and physico-mechanical properties of 06Kh18сh steel by depth in the process of cementation in a pasty carburizer was investigated. The main advantages and disadvan­tages of the selected mode of chemical and thermal treatment were determined. The expediency of cementation of high-chromium two-phase steels to improve significantly their physico-mechanical and operational properties was confirmed.

References

  1. I. Javorskyj, I. Matsko, R. Yuzefovych, O. Lychak, and R. Lys, “Methods of hidden periodicity discovering for gearbox fault detection,” Sensors, 21 (2021). Article number 6138. https://doi.org/10.3390/s21186138
  2. I. Yavorskyj, R. Yuzefovych, I. Kravets, and I. Matsko, “Properties of characteristics estimators of periodically correlated random processes in preliminary determination of the period of correlation,” Radioelectronics and Communication Systems, 55, Is. 8, 335-348 (2012). https://doi.org/10.3103/S0735272712080018
  3. H. Nykyforchyn, V. Kyryliv, and O, Maksymiv, “Effect of nanostructurisation for structural steels on their wear hydrogen embittlement resistance,” Solid State Phenomena, 225, 65-70 (2015). https://doi.org/10.4028/www.scientific.net/SSP.225.65
  4. V. Kyryliv, O. Maksymiv, V. Gurey, I. Hurey, Y. Kyryliv, and O. Zvirko, “The mode deformation effect on surface nanocrystalline structure formation and wear resistance of steel 41Cr4,” Coatings, 13, Is. 2 (2023). Atricle number 249. https://doi.org/10.3390/coatings13020249
  5. V. I. Kyryliv, B. P. Chaikovs’kyi, O. V. Maksymiv, A. V. Shal’ko, and P. Ya. Sydor, “Serviceability of 60KH2M roll steel with surface nanostructure,” Mater. Sci., 52, No. 6, 848-853 (2017). https://doi.org/10.1007/s11003-017-0030-x
  6. V. Kyryliv, Y. Kyryliv, and N. Sas, “Formation of surface ultrafine grain structure and their physical and mechanical characteristics using vibration-centrifugal hardening,” Adv. in Mat. Sci. and Eng., 2018 (2018). Article number 3152170. https://doi.org/10.1155/2018/3152170
  7. V. Gurey, P. Maruschak, I. Hurey, V. Dzyura, T. Hurey, and W. Wojtowicz, “Dynamic analysis of the thermo-deformation treatment process of flat surfaces of machine parts,” J. of Manufacturing and Mat. Process., 7, Is. 3 (2023). Article number 101. https://doi.org/10.3390/jmmp7030101
  8. V. V. Golovko, V. A. Kostin, and V. V. Zhukov, “Influance of nanomodification on the micro-structure of the metal of welded joints of low-alloy steels,” Mater. Sci., 59, No. 6, 762-769 (2024). https://doi.org/10.1007/s11003-024-00838-y
  9. I. B. Ivasenko, O. R. Berehulyak, T. S. Mandziy, V. M. Posuvailo, and R. A. Vorobel, “Modeling of laser-modified layer reinforced with silicon carbide particles on an aluminium alloy,” Mater. Sci., 59, No. 6, 754-761 (2024). https://doi.org/10.1007/s11003-024-00837-z
  10. V. Babak, N. Fialko, V. Shchepetov, S. Kharchenko, Y. Hladkyi, and S. Bys, “Self-lubricating glass composite nanocoatings,” Mater. Sci., 59, No. 1, 33-39 (2023). https://doi.org/10.1007/s11003-023-00740-z
  11. M. Bembenek, V. Kopei, L. Ropyak, and K. Levchuk, “Stressed state of chrome parts during diamond burnishing,” Metallofizika i Noveishie Tekhnologii [in Russian], 45, Is. 2, 239-250 (2023). https://doi.org/10.15407/mfint.45.02.0239
  12. A. I. Balitskii, M. R. Havrilyuk, V. O. Balitska, V. O. Kolesnikov, and L. M. Ivaskevych, “Increasing turbine hall safety by using fire-resistant, hydrogen-containing lubricant cooling liquid for rotor steel mechanical treatment,” Energies, 16, Is. 1 (2023). Article number 535. https://doi.org/10.3390/en16010535
  13. O. A Balitskii, V. O. Kolesnikov, A. I. Balitskii, J. J. Eliasz, and M. R. Havrylyuk, “Hydrogen effect on the high-nickel surface steel properties during machining and wear with lubricants,” Archives of Mat. Sci. and Eng., 104, Is. 2, 49-57 (2020). https://doi.org/10.5604/01.3001.0014.4894
  14. T. N. Kalichak, V. I. Kyryliv, and S. V. Fenchin, “Mechanopulsed hardening of long compo-nents of hydraulic cylinder rod types,” Mater. Sci., 25, No. 1, 96-99 (1989). https://doi.org/10.1007/BF00727938
  15. I. P. Shatskyi, L. Y. Ropyak, and M. V. Makoviichuk, “Strength optimization of a two-layer coating for the particular local loading conditions,” Strength of Mater., 48, Is. 5, 726-730 (2016). https://doi.org/10.1007/s11223-016-9817-5
  16. E. J. David and D. R. James, Corrosion Science and Technology, CRC Press., Boca Raton (2010).
  17. N. M. Ghoniem, G. Po, and S. Sharafat, “Deformation mechanisms in ferritic/martensitic steels and the impact on mechanical design,” J. of Nuclear Mater., 441, Is. 1-3, 704-712 (2013). https://doi.org/10.1016/j.jnucmat.2013.03.045
  18. H. P. Shen, T. C. Lei, and J. Z. Liu, “Microscopic deformation behaviour of martensitic-ferritic dual-phase steels,” Mat. Sci. and Technol., 2, Is.1, 28-33 (1986). https://doi.org/10.1179/026708386790123576
  19. Z. W. Hsiao, B. Kuhn, S. M. Yang, L. C. Yang, S. Y. Huang, L. Singheiser, J. C. Kuo, and D. Y. Lin, “The influence of deformation on the precipitation behavior of a ferritic stainless steel,” in: Proc. 10th Liége Conf. on Materials for Advanced Power Engineering (Liége, Belgium, 14-17 September 2014) (2014), pp. 349-358.
  20. Y. Vyshnepolskyi, D. Pavlenko, D. Tkach, and Y. Dvirnyk, “Parts diamond burnishing process regimes optimization made of INCONEL 718 alloy via selective laser sintering method,” in: Proc. 2020 IEEE 10th Int. Conf. on “Nanomaterials: Applications and Properties”, NAP 2020 (Sumy, Ukraine, 9-13 November 2020) (2020). Article number 166392. https://doi.org/10.1109/NAP51477.2020.9309661
  21. Venu Madhav BSR, Ahad Mohiuddin A., and Atifuddin M., “Effect of carburization, on the mechanical properties of EN-8 steel in different quenching medium, at different quenching time intervals,” Int. J. of Metallurgical & Mater. Sci. and Eng., 7, Is.4, 1-12 (2017). https://doi.org/10.24247/ijmmsedec20171
  22. V. G. Mishchenko, O. I. Bulakh, and V. I. Menyailo, “Surface hardening of chromium martensitic-ferritic steels of 04…08Х18ch-type,” Novi Materialy i Tekhnologiyi v Metalurgiyi ta Mashynobuduvanni [in Uktainian], Is. 2, 41-45 (2017).
  23. V. G. Mishchenko, and A.I. Melyailo, “Control of carburizing processes and decarburizing of special steels during chemicothermal and thermal treatment,” Obrabotla Materialov Davleniyem [in Russian], Pratsi Donbaskoyi Natsionalnoyi Mashymobudivnoi Academiyi, Kramatorsk, Is. 2 (41), 285-292 (2015).
  24. Zeeshan Hyder Wani and Neeraj Kumar, “A review on carburizing temperature and the me-chanical behaviour of mild steel,” Dogo Rangsang Res. J, 10, Is.9, 115-127 (2020).
  25. A. A. Salih, M. Z. Omar, S. Junaidi, and Z. Sajuri, “Effect of different heat treatment on the SS440C martensitic stainless steel,” Australian J. of Basic and Appl. Sci., 5, Is.12, 867-871 (2011).
  26. V. N. Zhuravlev, and O. I. Nikolayeva, Engineering Steels [in Russian], Mashinostroyeniye, Moscow (1981).