ISSN 3041-1815. Physicochemical Mechanics of Materials. 2025.
Volume 61, Issue 3
Structure, elastic modulus and corrosion resistance of Ti–20Nb–20Zr alloy
Keywords
titanium alloy, phase-structural state, corrosion resistance, Hank’s solution.
Cite as
Lavrys S. M., Schwab S. L., Danyliak M.-O. M., Voron M. M., Proskurnyak R. V., and Pohrelyuk I. M. Structure, elastic modulus and corrosion resistance of Ti–20Nb–20Zr alloy. Physicochemical Mechanics of Materials. 2025. 61(3), 126-136.
https://doi.org/10.15407/pcmm2025.03.126
Abstract
The Ti–20Nb–20Zr β-rich titanium alloy for medical applications obtained by electron beam casting was studied. According to electrochemical studies in simulated body fluid (Hank’s solution), it was found that the Ti–20Nb–20Zr alloy had better anti-corrosion properties (higher corrosion potential and lower corrosion current) than widely used alloys such as commercially pure Ti, Ti–6Al–4V and Ti–6Al–3Nb–2Zr alloys. The main corrosion mechanisms of the studied alloys in Hank’s solution were considered and the influence of the phase-structural state on their electrochemical behavior was assessed
References
- J. Quinn, R. McFadden, C.-W. Chan, and L. Carson, “Titanium for orthopedic applications: An overview of surface modification to improve biocompatibility and prevent bacterial biofilm formation,” Science, 23 (2020). Article number 101745. https://doi.org/10.1016/j.isci.2020.101745
- I. Golvano, I. Garcia, A. Conde, W. Tato, and A. Aginagalde, “Influence of fluoride content and pH on corrosion and tribocorrosion behaviour of Ti13Nb13Zr alloy in oral environment,” J. Mech. Behav. Biomed. Mater., 49, 186-196 (2015). https://doi.org/10.1016/j.jmbbm.2015.05.008
- K. Ronoh, F. Mwema, S. Dabees, and D. Sobola, “Advances in sustainable grinding of different types of the titanium biomaterials for medical applications: A review,” Biomed. Eng. Adv., 4 (2022). Article number 100047. https://doi.org/10.1016/j.bea.2022.100047
- K. Szymkiewicz, J. Morgiel, Ł. Maj, M. Pomorska, M. Tarnowski, O. Tkachuk, I. Pohrelyuk, and T. Wierzchoń, “Effect of nitriding conditions of Ti6Al7Nb on microstructure of TiN surface layer,” J. Alloys Compd., 845 (2020). Article number 156320. https://doi.org/10.1016/j.jallcom.2020.156320
- C. Siemers, M. Bäker, F. Brunke, D. Wolter, and H. Sibum, “Titanium in medical and dental applications,” in: Francis H. Froes, and Ma Qian (editors) Aluminum- and Vanadium-Free Titanium Alloys for Application in Medical Engineering, Woodhead Publishing (2018), pp. 477-492. https://doi.org/10.1016/B978-0-12-812456-7.00021-4
- O. P. Ostash, V. Ya. Podhurska, B. D. Vasyliv, L. D. Kulak, M. M. Kuzmenko, and A. E. Fisk, “Strength and corrosion-fatigue crack-growth resistance of alloys of the Ti-Nb-Zr-Si system intended for biomedical purposes,” Mater. Sci., 55, No. 5, 648-655 (2020). https://doi.org/10.1007/s11003-020-00355-8
- R. B. Schifman, and D. R. Luevano, “Aluminum toxicity: evaluation of 16-year trend among 14 919 patients and 45 480 results,” Arch. Pathol. Lab. Med., 142, 742-746 (2018). https://doi.org/10.5858/arpa.2017-0049-OA
- О. М. Shevchenko, L. D. Kulak, M. M. Kuzmenkо, A. V. Kotko, and S. O. Firstov, “Investigation of structure of the quenched cast biocompatible Ti-18Nb-хSi alloys,” Metallofizika i Noveishie Tekhnologii [in Russian], 39, 823-837 (2007). https://doi.org/10.15407/mfint.39.06.0823
- N. M. Eldabah, A. Shoukry, W. Khair-Eldeen, S. Kobayashi, and M. A.-H. Gepreel, “Design and characterization of low Young’s modulus Ti-Zr-Nb-based medium entropy alloys assisted by extreme learning machine for biomedical applications,” J. Alloys Compd., 968 (2023). Article number 171755. https://doi.org/10.1016/j.jallcom.2023.171755
- T. Lee, S. Lee, I.-S. Kim, Y. H. Moon, H. S. Kim, and C. H. Park, “Breaking the limit of Young’s modulus in low-cost Ti-Nb-Zr alloy for biomedical implant applications,” J. Alloys Compd., 828 (2020). Article number 154401. https://doi.org/10.1016/j.jallcom.2020.154401
- M. Metikos̆-Huković, A. Kwokal, and J. Piljac, “The influence of niobium and vanadium on passivity of titanium-based implants in physiological solution,” Biomaterials, 24, 3765-3775 (2023). https://doi.org/10.1016/S0142-9612(03)00252-7
- S. Lavrys, M.-O. Danyliak, I. Pohrelyuk, and O. Tkachuk, “Improving corrosion resistance of additively manufactured Ti6Al4V titanium alloy by post heat treatment,” Procedia Structural Integrity, 53, 246-253 (2024). https://doi.org/10.1016/j.prostr.2024.01.030
- L. Chenghao, J. Li’nan, Y. Chuanjun, and H. Naibao, “Crevice corrosion behavior of CP Ti, Ti-6Al-4V alloy and Ti-Ni shape memory alloy in artificial body fluids,” Rare Metal Mat. Eng., 44, 781-785 (2025). https://doi.org/10.1016/S1875-5372(15)30046-1
- S. L. Schwab, R. V. Selin, A. A. Babinets, M. M. Voron, and T. B. Yanko, “The effect of heat treatment on Ti-Zr-Nb alloy multilayer joints, obtained by the WAAM with filler cored wire,” in: Proc. of the 7th Int. Conf. on Welding and Related Technologies (WRT 2024), (2025), pp. 14-18. https://doi.org/10.1201/9781003518518-3
- Y. Xiao, N. Dai, Y. Chen, J. Zhang, and S.-W. Choi, “On the microstructure and corrosion behaviors of selective laser melted CP-Ti and Ti-6Al-4V alloy in Hank’s artificial body fluid,” Mater. Res. Express., 6 (2019). Article number 126521. https://doi.org/10.1088/2053-1591/ab54d5
- Y. Yang, B. Wang, B. Su, L. Luo, L. Wang, Y. Su, Y. Xu, H. Huang, J. Guo, and H. Fu, “Investigation on corrosion behavior of Zr-bearing TA10-based titanium alloys,” Corr. Sci., 221 (2023). Article number 111354. https://doi.org/10.1016/j.corsci.2023.111354
- W.-F. Ho, S.-C. Wu, S.-K. Hsu, Y.-C. Li, and H.-C. Hsu, “Effects of molybdenum content on the structure and mechanical properties of as-cast Ti-10Zr-based alloys for biomedical applications,” Mater. Sci. Eng. C, 32, 517-522 (2012). https://doi.org/10.1016/j.msec.2011.12.003
- S. Ehtemam-Haghighi, Y. Liu, G. Cao, and L.-C. Zhang, “Influence of Nb on the β→a″ martensitic phase transformation and properties of the newly designed Ti-Fe-Nb alloys,” Mater. Sci. Eng. C, 60, 503-510 (2016). https://doi.org/10.1016/j.msec.2015.11.072
- H. Lu, Y. Tang, H. Shi, B. Li, P. Ji, Z. Xu, S. Liang, J. Zhang, S. Zhang, X. Zhang, and R. Liu, “Effect of Zr addition on mechanical properties and corrosion behavior of Ti-6Al-7Nb-xZr (x = 0, 5, 10, 15, 20 wt%) alloy,” J. Alloys Compd., 998 (2024). Article number 174994. https://doi.org/10.1016/j.jallcom.2024.174994
- G. C. Cardoso, P. A. B. Kuroda, and C. R. Grandini, “Influence of Nb addition on the struc-ture, microstructure, Vickers microhardness, and Young’s modulus of new β Ti-xNb-5Mo alloys system,” JMR&T, 25, 2238-7854 (2023). https://doi.org/10.1016/j.jmrt.2023.06.168
- S. M. Lavrys, I. M. Pohrelyuk, and K. S. Shliakhetka, “Corrosion resistance of additively manufactured titanium alloys in hydrochloric acid,” Mater. Sci., 58, No. 5, 585-590 (2023). https://doi.org/10.1007/s11003-023-00702-5
- X. Qin, H. Yang, Y. Zhao, S. Wan, X. Zhao, T. Yu, X. Wang, and Z. Zhang, “Investigation of the microstructural characteristics of laser-cladded Ti6Al4V titanium alloy and its corrosion behavior in simulated body fluid,” Mater. Today Commun., 41 (2024). Article number 110780. https://doi.org/10.1016/j.mtcomm.2024.110780
- L. Chen, M. Liang, W. Wan, J. Tang, B. Lin, X. Yang, Y. Chen, and Y. Chen, “Corrosion of commercial pure titanium and two titanium alloys in extremely high-chloride and high-alkali seawater electrolysis environment,” J. of Alloys and Compounds, 1020 (2025). Article number 179431. https://doi.org/10.1016/j.jallcom.2025.179431
- C. Xu, X. Zheng, F. An, X. Zhou, Y. Cai, and B. Zhang, “Effect of V content on the corrosion resistance of wire arc additive manufactured Ti-6Al-xV alloys,” Mater. Trans., 64, 2606-2614 (2023). https://doi.org/10.2320/matertrans.MT-M2023031
- S. Tamilselvi, V. Raman, and N. Rajendran, “Corrosion behaviour of Ti-6Al-7Nb and
Ti-6Al-4V ELI alloys in the simulated body fluid solution by electrochemical impedance spectroscopy,” Electrochim. Acta, 52, 839-846 (2006). https://doi.org/10.1016/j.electacta.2006.06.018
- C. C. Liu, L. M. Zhang, Z. Liu, A. L. Ma, Z. X. Liu, and Y. G. Zheng, “Exploring the impact of Al alloying on microstructure and hot nitric acid corrosion resistance of Ti-xAl (x = 0, 1, 2, 3, 4, 5) alloys,” Corros. Sci., 232 (2024). Article number 112010. https://doi.org/10.1016/j.corsci.2024.112010
- O. V. Shapovalov, O. M. Shapovalova, and T. I. Ivchenko, “Corrosion and mechanical properties of titanium alloyed with aluminum, iron, and molybdenum,” Mater. Sci., 42, No. 5, 615-619 (2006). https://doi.org/10.1007/s11003-006-0124-3
- D. D. Macdonald, “Point defect model for passive state,” J. Electrochem. Soc., 139, 3434-3449 (1992). https://doi.org/10.1149/1.2069096
- M. Abdel-Hady, K. Hinoshita, and M. Morinaga, “General approach to phase stability and elastic properties of β-type Ti-alloys using electronic parameters,” Scr. Mater., 55, 477-480 (2006). https://doi.org/10.1016/j.scriptamat.2006.04.022
- Y. Okazaki, A. Ito, T. Tateishi, and Y. Ito, “Effect of alloying elements on anodic polarization properties of titanium alloys in acid solutions,” Mater. Trans. JIM, 35, 58-66 (1994). https://doi.org/10.2320/matertrans1989.35.58
- M. Morinaga, A Quantum Approach to Alloy Design, Elsevier (2019). https://doi.org/10.1016/B978-0-12-814706-1.00004-2