ISSN 3041-1815. Physicochemical Mechanics of Materials. 2025.
Volume 61, Issue 2
Transformation of structure and properties of Al–Zn–Mg–Cu alloy under complex processing. Part. I. Microstructure
Keywords
7075 alloy, twin-roll casting, hot rolling, quenching, aging, microstructure.
Cite as
Pryhunova A. H., Nohovitsyn О. V., Aiupova Т. А., Abolikhina O. V., and Nosko О. А. Transformation of structure and properties of Al–Zn–Mg–Cu alloy under complex processing. Part. I. Microstructure. Physicochemical Mechanics of Materials. 2025. 61(2), 005-013.
https://doi.org/10.15407/pcmm2025.02.005
Abstract
The structure formation of the 7075 Al–Zn–Mg–Cu alloy with a maximum allowable zinc content (6.1 mass%) and a crystallization range of 162°C was studied during the complex technological process “twin-roll casting–hot rolling–heat treatment”. It is shown that the structure of the cast strip during twin-roll casting is non-dendritic, with dispersed intermetallic precipitates present within the grains. At the grain boundaries, non-equilibrium eutectics are formed. Hot rolling with a deformation degree of ε = 64–88% causes the orientation of the primary solid solution (Al) crystals in the rolling direction process and a reduction in their size in the plane perpendicular to the strip surface. The volume fraction and size of intermetallics decrease monotonically due to the mechanical effects of rolling and the partial dissolution of strengthening phases in the solid solution (Al). During heat treatment, the size and shape parameter of dendritic cells (Al) and intermetallics decrease due to recrystallization and spheroidization processes. After quenching and natural aging, the supersaturation of the solid solution increases as a result of the dissolution of the strengthening phases located on the grain boundaries (Al), the iron-containing intermetallics of crystallization genesis and spheroidization of secondary intermetallics being preserved. During artificial aging, the quantity and size of eutectic and secondary intermetallics increase, but their shape parameter decreases. This structural transformation differs from that observed in traditional processing technology, with smaller grain size, higher dispersion, and a more uniform distribution of intermetallic phases, as well as the absence of macrosegregations of casting heterogeneities. This is primarily due to the hereditary influence of high cooling rate from the liquid state (v ≈ 103 °С/s) at the initial stage of the complex process.
References
- C. R. Killmore, H. Greely, and A. Phillips, “Development of ultra-thin cast strip products the CASTRIP-process,” Mater. Forum., 32, 12-28 (2008).
- P. Campbell, W. Blejde, R. Mahapatra, R. Wechsler, and G Gillen, “The сastrip process – direct casting of steel sheet at nucor Crawfordsville,” Iron and Steel Technol., 56 (2005).
- C. Gras, N. Meredith, and J. D. Hunt, “Microdefects for mation during the roll casting of Al-Mg-Mn aluminum alloys,” J. Mater. Process. Technol., 167, 62-72 (2005). https://doi.org/10.1016/j.jmatprotec.2004.09.084
- M. Ferry, Direct Strip Casting of Metals and Alloys, Boca Raton: CRC Press (2006). https://doi.org/10.1533/9781845691660
- Ch. Gras, M. Meredith, K. Gatenby, and J. D. Hund, “Defect formation in twin roll-cast AA 3xxx and 5xxx series aluminium alloys,” Mater. Sci. Forum, 396-402, 89-94 (2002). https://doi.org/10.4028/www.scientific.net/MSF.396-402.89
- T. Haga, M. Ikawa, H. Wtari, and S. Kumai, “Aluminium alloys strip casting usingan unequal diameter twin roll caster,” J. Mater. Process. Technol., 172, 271-276 (2006). https://doi.org/10.1016/j.jmatprotec.2005.10.007
- M. Slamova and O. Voda, “New horizons for twin-roll casting,” Aluminium Int. Today, 85-88 (2001).
- P.-Y. Menet, F. Basson, K. Maiwald, R. Cayol, and M. Bosch, “Strip Casting Technology. A Key to Product Quality,” in: Proc. of Int. Melt Quality Workshop, pp. 25-29 (2001).
- A. Yu. Grydin, M. Schaper and V. N. Dabchenko, “Production of strips from high-strength aluminum alloys by roller casting-rolling,” Obrabotka Metalov Davleniyem [in Russian], Is. 3(28), 184-194 (2011).
- A. V. Nogovitsyn, A. V. Narivskyi, I.R. Baranov, V. P. Shklyarenko, and V. I. Shapoval, “Technology of producing sheet metal from alloy D16 on a roller casting unit,” Protsesy Littiya [n Russian], Is., 37-42 (2017).
- O. Grydin, S. Bondarenko, M. Stolbchenko, and M. Schaper, “Rolling of flat aluminum strips with tailored mechanical properties,” Mater. Sci. Forum, 854, 87-92 (2016). https://doi.org/10.4028/www.scientific.net/MSF.854.87
- S. Bondarenko, M. Stolbchenko, M. Schaper, and O. Grydin, “Numerical analysis of twin-roll casting of strips with profiled cross-section,” Mater. Res., 21, Is. 4 (2018). https://doi.org/10.1590/1980-5373-mr-2017-1098
- O. V. Nogovitsyn, A. S. Nuradinov, A. H. Pryhunova,V. Z. Kutsova, T. A. Ayupova, and I. A. Nuradinov, “Structure and properties of D16 alloy cast strip in the technological chain “roll casting-hot rolling-heat treatment,” Metaloznavstvo ta Obrobka Metaliv [in Ukrainian], 26, Is. 2, 49-59 (2020). https://doi.org/10.15407/mom2020.02.049
- I. J. Polmear, Light Alloys – From Traditional Alloys to Nanocrystalls, Monash University, Melbourne (2006).
- V. M. Beletskyi, and H. A. Krivov, Aluminum Alloys (Composition, Properties, Application), I. N. Fridlyander (editor), Kyiv, ZAO “KPMINTEKh” (2005).
- Recent Trends in Processing and Degradation of Aluminum Alloys, A. Zaki (editor), IntechOpen, London, (2016).
- Practice for Temperature Calibration of Differential Scanning Calorimeters and Thermal Analyzers. ASTM Standard: E 967-97.
- S. A. Saltukov, Stereometric Metallography [in Russian], Metallurgiya, Moscow (1976).
- F. Y. Xie, X. Y. Yan, L. Ding, F. Zhang, S. L. Chen, M. Chu, and Y. A. Chang, “A study of microstructure and microsegregation of aluminum 7050 alloy,” Mater. Sci. Eng. A, 335, 144-153 (2003). https://doi.org/10.1016/S0921-5093(03)00056-X
- L. F. Mondolfo, Aluminium Alloys: Structure and Properties, Butterworths London (1976). https://doi.org/10.1016/B978-0-408-70932-3.50008-5
- S. T. Lim, I. S. Eun, and S. W. Nam, “Control of equilibrium phases (M, T, S) in the modified aluminum alloy 7175 for thick forging applications,” Mater. Trans., 44, Is. 1, 181-187 (2003). https://doi.org/10.2320/matertrans.44.181
- T. Wang, Z.-M. Yin, and Q. Sun, “Effect of homogenization treatment on microstructure and hot workability of high strength 7B04 aluminum alloy,” Trans. Nonferrous Met. Soc. China, 17, 335-339 (2007). https://doi.org/10.1016/S1003-6326(07)60094-6
- L.-T Jiang, G.-H Wu, W.-S. Yang, Y.-G. Zhao, and S.-S. Liu, “Effect of heat treatment on microstructure and dimensional stability of ZL114A aluminum alloy,” Trans. Nonferrous Met. Soc. China, 20, 2124-2128 (2010). https://doi.org/10.1016/S1003-6326(09)60428-3
- S. T. Lim, Y. Y. Lee, and I. S. Eun, “Microstructural evolution during ingot preheat in 7xxx aluminum alloys for thick semiproduct applications,” Mater. Sci. Forum, 519-521, 549-554 (2006). https://doi.org/10.4028/www.scientific.net/MSF.519-521.549
- Yu. N. Taran, A. H. Pryhunova, S. S. Petrov, and Te. I. Korzh, “Distribution of zinc in cast complex aluminum-silicon alloys,” Doklady Aademii Nauk UkrSSR [in Russian, Is. 12, 72-75 (1986).
- Li Nian-kui and Cui Jian-zhong, “Microstructural evolution of high strength 7B04 ingot during homo¬genization treatment,” Trans. Nonferrous Met. Soc. China, 18, Is. 4, 769-773 (2008). https://doi.org/10.1016/S1003-6326(08)60132-6
- A. G. Prygunova, O. A. Shcheretskiy, M. V. Koshelev, V. D. Babuk, and E. A. Zhidkov, “Thermodynamic modelling and thermal analysis of AK5M2 alloy with 0,8-3,3% iron,” Metallophysics and Adv. Technol., 44, Is. 5, 671-689 (2022). https://doi.org/10.15407/mfint.44.05.0671
- Behzad Binesh and Mehrdad Aghaie-Khafri, “Phase evolution and mechanical behavior of the semi-solid SIMA processed 7075 aluminum alloy,” Metals, 6, Is. 3, 42 (2016). https://doi.org/10.3390/met6030042